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US 2023/0053984 A1Published application
Positive active material, preparation method therefor, and lithium secondary battery having positive electrode comprising same
AssigneeSm Lab Co., Ltd.
InventorsMin Ho SEO, Ji Young KIM
Life of this patent
Estimating the term…
Abstract
The present disclosure relates to a positive active material including a lithium transition metal oxide substituted with Na, W, Mg, Ti, and S, a method of preparing the same, and a lithium secondary battery having a positive electrode including the positive active material.
Claims20
A positive active material comprising:
- a lithium transition metal oxide represented by Formula 1:
- Li1-xNaxM1-(α+β+γ)WαMgβTiγO2-aSa, Formula 1:
- wherein in Formula 1,
- M includes one or more elements selected from alkali metal elements, alkali earth metal elements, transition metal elements, post-transition metals, and non-metallic elements, other than W, Mg, Ti, Na, and S
- 0<x≤0.01, 0<α≤0.01, 0<β≤0.005, 0<γ≤00.005, 0<a≤0.01, and 0<α+β+γ≤0.02.
2 more elements
A method of preparing a positive active material, the method comprising:
- obtaining a precursor of a lithium transition metal oxide by mixing a Li-containing compound, a Na-containing compound, a W-containing compound, a Mg-containing compound, a Ti-containing compound, an M-containing compound, and an S-containing compound;
- and
- heat-treating the precursor to obtain a positive active material comprising a lithium transition metal oxide represented by Formula 1.
- Li1-xNaxM1-(α+β+γ)WαMgβTiyO2-aSa, Formula 1:
- wherein in Formula 1,
- M includes one or more elements selected from alkali metal elements, alkali earth metal elements, transition metal elements, metalloid elements, and non-metallic elements, other than W, Mg, Ti, Na, and S, and
- 0<x≤0.01, 0<α≤0.01, 0<β≤0.005, 0<γ≤0.005, 0<a≤0.01, and 0<α+β+γ≤0.02.
4 more elements
Dependencies are inferred from the claim text.