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US 2023/0053936 A1Published application
Methanol Production via Dry Reforming and Methanol Synthesis in a Vessel
AssigneeSaudi Arabian Oil Company
InventorsBandar Solami, Aqil Jamal, Kunho Lee
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Abstract
A system and method for producing methanol via dry reforming and methanol synthesis in the same vessel, including converting methane and carbon dioxide in the vessel into syngas including hydrogen and carbon monoxide via dry reforming in the vessel, cooling the syngas via a heat exchanger in the vessel, and synthesizing methanol from the syngas in the vessel.
Claims24
A method of producing methanol via dry reforming and methanol synthesis, the method comprising:
- providing feed comprising methane and carbon dioxide to a dry reforming section in a vessel, the vessel comprising a vessel wall, wherein the dry reforming section and a methanol synthesis section are enclosed within the vessel in an interior of the vessel to inside of the vessel wall;
- converting methane and carbon dioxide in the vessel into syngas comprising a molar ratio of hydrogen (H2) and carbon monoxide by dry reforming via dry reforming catalyst in the dry reforming section in the vessel;
- injecting H2 into the syngas in the reactor vessel in response to specifying to increase a molar ratio of H2 to carbon monoxide of the syngas in the reactor vessel, wherein the H2 injected is injected into a discharge portion of the dry reforming section or into a heat exchanger in the vessel that receives the syngas from the dry reforming section;
- cooling the syngas via the heat exchanger in the vessel, wherein the heat exchanger is disposed between the dry reforming section and the methanol synthesis section;
- synthesizing methanol from the syngas discharged from the heat exchanger via methanol synthesis catalyst in the methanol synthesis section in the vessel;
- discharging effluent from the vessel, the effluent comprising the methanol;
- processing the effluent as discharged to remove components from the effluent to give the methanol as product, the components comprising H2, carbon monoxide, and carbon dioxide;
- and
- recycling carbon dioxide removed from the effluent to the dry reforming section.
6 more elements
A method of producing methanol, comprising:
- converting methane and carbon dioxide via a dry reforming catalyst in a dry reforming section in a reactor vessel into syngas comprising hydrogen (H2) and carbon monoxide, wherein the converting comprises dry reforming;
- flowing the syngas from the dry reforming section through a heat exchange section in the reactor vessel to cool the syngas with a cooling medium in the heat exchange section;
- injecting H2 into the syngas in the reactor vessel in response to specifying to increase a molar ratio of H2 to carbon monoxide of the syngas in the reactor vessel, wherein the H2 injected is injected into a discharge portion of the dry reforming section or into the heat exchange section;
- flowing the syngas as cooled from the heat exchange section to a methanol synthesis section in the reactor vessel, wherein the dry reforming section and the methanol synthesis section are enclosed within the reactor vessel in an interior of the reactor vessel;
- synthesizing methanol from the syngas via a methanol synthesis catalyst in the methanol synthesis section;
- discharging effluent comprising the methanol from the reactor vessel;
- processing the effluent to remove hydrogen, carbon monoxide, and carbon dioxide from the effluent to give the methanol as product;
- and
- providing carbon dioxide removed from the effluent to the dry reforming section.
6 more elements
A methanol production system comprising:
- a reactor vessel comprising:
- a feed inlet to receive a feed comprising methane and carbon dioxide;
- a dry reforming section comprising a dry reforming catalyst in the reactor vessel to convert the methane and the carbon dioxide into syngas comprising hydrogen and carbon monoxide;
- a heat exchange section comprising a heat exchanger in the reactor vessel to receive the syngas from the dry reforming section and cool the syngas with a cooling medium;
- and
- a methanol synthesis section comprising a methanol synthesis catalyst in the reactor vessel to synthesize methanol from the syngas and discharge an effluent comprising the methanol from the reactor vessel.
3 more elements
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Dependencies are inferred from the claim text.