Chemically amplified negative resist composition and resist pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsKeiichi Masunaga, Satoshi Watanabe, Masaaki Kotake, Masaki Ohashi
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Abstract
A chemically amplified negative resist composition comprising (A) a sulfurane or selenurane compound having formula (A1) wherein M is sulfur or selenium and (B) a base polymer containing a polymer comprising repeat units having formula (B1) is provided. The resist composition exhibits a high resolution during pattern formation and forms a pattern with minimal LER or LWR.
Claims13
A chemically amplified negative resist composition comprising (A) a sulfurane or selenurane compound having the following formula (A1) and (B) a base polymer containing a polymer comprising repeat units having the following formula (B1),
- wherein R1 to R4 are each independently a C1-C20 hydrocarbyl group which may contain a heteroatom, R1 and R2 may bond together to form a ring with L1 and M to which they are attached, R1 and R2, and R3 and R4 may bond together to form spiro rings with M as the spiro atom,
- L1 and L2 are each independently —O— or —N(R)—, R is hydrogen or a C1-C20 hydrocarbyl group which may contain a heteroatom, and
- M is sulfur or selenium,
- wherein RA is hydrogen, fluorine, methyl or trifluoromethyl,
- R11 is halogen, an optionally halogenated C2-C8 saturated hydrocarbylcarbonyloxy group, optionally halogenated C1-C6 saturated hydrocarbyl group, or optionally halogenated C1-C6 saturated hydrocarbyloxy group,
- A1 is a single bond or a C1-C10 saturated hydrocarbylene group in which any constituent —CH2— may be replaced by —O—,
- s is 0 or 1, w is an integer of 0 to 2, a is an integer satisfying 0≤a≤5+2w−b, and b is an integer of 1 to 3.
Dependencies are inferred from the claim text.