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US 2022/0037695 A1Published application
Composition for polymer electrolyte and lithium secondary battery including polymer electrolyte prepared therefrom
AssigneeLG Chem, Ltd.
InventorsKyoung Ho AHN, Sol Ji PARK, Jun Hyeok HAN, Chul Haeng LEE, Jung Hoon LEE
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Abstract
The present invention relates to a composition for a polymer electrolyte which includes a polymerizable oligomer capable of forming an excellent crosslink during a polymerization reaction. Also, the present invention relates to a polymer electrolyte, which may ensure high oxidation stability and ionic conductivity by using the composition for a polymer electrolyte, and a lithium secondary battery including the same.
Claims10
A composition for a polymer electrolyte, comprising:
- a lithium salt, an organic solvent, a polymerization initiator, and a polymerizable oligomer,
- wherein the polymerizable oligomer comprises at least one of an oligomer represented by Formula 1 or an oligomer represented by Formula 2:
- wherein, in Formula 1,
- R′ and R″ are each independently an aliphatic hydrocarbon group or an aromatic hydrocarbon group,
- R1 and R2 are each independently a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkylene group having 4 to 20 carbon atoms, a substituted or unsubstituted arylene group having 6 to 20 carbon atoms, a substituted or unsubstituted heterocycloalkylene group having 2 to 20 carbon atoms, —CO—O—R—, where R is an alkylene group having 1 to 10 carbon atoms, —R0—CO—, {where R0 is an alkylene group having 1 to 10 carbon atoms}, or —R3—O—R4—, where R3 and R4 are each independently a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms,
- Ra, Rb, Rc, and Rd are each independently hydrogen or an alkyl group having 1 to 3 carbon atoms,
- n is an integer of 1 to 100, and
- m is an integer of 1 to 100,
- a and c are each independently an integer of 0 to 2, and
- b and d are each independently an integer of 1 to 3,
- wherein, in Formula 2,
- R5, R6, R7, and R8 are each independently a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkylene group having 4 to 20 carbon atoms, a substituted or unsubstituted arylene group having 6 to 20 carbon atoms, a substituted or unsubstituted heterocycloalkylene group having 2 to 20 carbon atoms, —CO—O—Rj, where R is an alkylene group having 1 to 10 carbon atoms, —Rk—CO—, where Rk is an alkylene group having 1 to 10 carbon atoms, or —R12—O—R13—, where R12 and R13 are each independently a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms,
- R9, R10, and R11 are each independently an aliphatic hydrocarbon group or an aromatic hydrocarbon group,
- Re, Rf, Rg, and Rh are each independently hydrogen or an alkyl group having 1 to 3 carbon atoms,
- o is an integer of 1 to 100,
- p is an integer of 1 to 100, and
- q is an integer of 1 to 100,
- a1 and c1 are each independently an integer of 0 to 2, and
- b1 and d1 are each independently an integer of 1 to 3.
16 more elements
Dependencies are inferred from the claim text.