Back to results
US 2022/0033389 A1Published application
Insecticidal compounds
AssigneeSyngenta Crop Protection AG
InventorsAurelien BIGOT, André JEANGUENAT, Myriem EL QACEMI
Life of this patent
Estimating the term…
Abstract
Compounds of formula (I), wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, and their uses as insecticides.
Claims16
A compound of formula (I),
- wherein
- A1, A2, A3 and A4 are, independently of one another, C—H, C—R5 or N;
- R1 is selected from —(C0-C4alkyl)-C(═O)—C3-C6cycloalkyl, —(C0-C4alkyl)-O—C(═O)—C3-C6cycloalkyl, —(C0-C4alkyl)-O—C3-C6cycloalkyl, —R1aOR1aOR1b, —R1aOC(═O)R1b, —R1aOC(═O)OR1b, —R1aN(R1c)C(═O)OR1b, —R1aOC(═O)N(R1b)(R1c), —R1aC(═O)N(R1b)(R1c) and —S—C(═O)OR1b;
- R1a is —(CR1dR1e)n—;
- R1b and R1c are independently selected from H and C1-C4alkyl, wherein each alkyl group is unsubstituted or substituted with one to three halogen atoms or with a cyano group;
- R1d and R1e are independently selected from H and C1-C4alkyl;
- n is selected from 1, 2, 3 and 4;
- R2 is hydrogen, halogen, cyano, C1-C8alkyl or C1-C8alkyl substituted by one to three R6a, C1-C8haloalkyl or C1-C8haloalkyl substituted by one to three R6a, C1-C8alkoxy or C1-C8alkoxy substituted by one to three R6a, C3-C8cycloalkyl or C3-C8cycloalkyl substituted by one to three R6b, C3-C8cycloalkyl where one carbon atom is replaced by O, S, S(O) or SO2, or C3-C8cycloalkyl-C1-C8alkyl, C3-C8cycloalkyl-C1-C8alkyl where one carbon atom in the cycloalkyl group is replaced by O, S, S(O) or SO2, or C3-C8cycloalkyl-C1-C8haloalkyl, C2-C8alkenyl or C2-C8alkenyl substituted by one to three R6a, C2-C8haloalkenyl or C2-C8haloalkenyl substituted by one to three R6a, C2-C8alkynyl, C2-C8haloalkynyl, phenyl, phenyl substituted by one to three R7, phenyl-C1-C4alkyl, phenyl-C1-C4alkyl wherein the phenyl moiety is substituted by one to three R7, 5-6 membered heteroaryl, 5-6 membered heteroaryl substituted by one to three R7, 5-6 membered heteroaryl-C1-C4alkyl or 5-6 membered heteroaryl-C1-C4alkyl wherein the heteroaryl moiety is substituted by one to three R7, —NH(R8), —N(R8)(R9), —OR10, —SR10, —S(O)R10, —S(O)2R10, COR10, COOR10;
- R3 is C1-C8haloalkyl;
- R4 is phenyl or phenyl substituted by one to three R6b or pyridine or pyridine substituted by one to three R6b;
- R5 is independently halogen, cyano, nitro, C1-C8alkyl, C3-C8cycloalkyl, C1-C8haloalkyl, C2-C8alkenyl, C2-C8haloalkenyl, C2-C8alkynyl, C2-C8haloalkynyl, C1-C8alkoxy, C1-C8haloalkoxy, or C1-C8alkoxycarbonyl-, or two R5 on adjacent carbon atoms together form a —CH═CH—CH═CH— bridge or a —N═CH—CH═CH— bridge;
- each R6a is independently halogen, cyano, nitro, amino, hydroxy, oxo, C1-C8alkylamino, hydroxyimino, C1-C8alkyloxyimino, di-C1-C8alkylamino, C1-C8alkoxy, acetyloxy, formyloxy, C1-C8haloalkoxy, C1-C4alkylthio or tri-(C1-C4alkyl)silyl;
- each R6b is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, amino, C1-C8alkylamino, di-C1-C8alkylamino, hydroxyl, C1-C4alkylthio, C1-C8alkoxy or C1-C8haloalkoxy;
- R7 is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, C1-C8alkoxy, or C1-C8haloalkoxy;
- R8 and R9 are independently hydrogen, cyano, C1-C8alkyl or C1-C8alkyl substituted by one to three R6a, C1-C8alkoxy, C1-C8haloalkoxy, C1-C8haloalkoxy substituted by one to three R6a, C1-C8alkoxy substituted by one to three R6a, C1-C8haloalkyl or C1-C8haloalkyl substituted by one to three R6a, C3-C8cycloalkyl or C3-C8cycloalkyl substituted by one to three R6b, C3-C8cycloalkyl where one carbon atom is replaced by O, S, S(O) or SO2, or C3-C8cycloalkyl-C1-C8alkyl, C3-C8cycloalkyl-C1-C8alkyl where one carbon atom in the cycloalkyl group is replaced by O, S, S(O) or SO2, or C3-C8cycloalkyl-C1-C8haloalkyl, C2-C8alkenyl or C2-C8alkenyl substituted by one to three R6a, C2-C8haloalkenyl or C2-C8haloalkenyl substituted by one to three R6a, C2-C8alkynyl, C2-C8haloalkynyl, phenyl, phenyl substituted by one to three R7, phenyl-C1-C4alkyl, phenyl-C1-C4alkyl wherein the phenyl moiety is substituted by one to three R7, 5-6 membered heteroaryl, 5-6 membered heteroaryl substituted by one to three R7, 5-6 membered heteroaryl-C1-C4alkyl or 5-6 membered heteroaryl-C1-C4alkyl wherein the heteroaryl moiety is substituted by one to three R7, or R8 and R9 together with the nitrogen atom can be linked through a C3-C8alkylene chain, a C3-C8alkylene chain substituted by one to three R6b or a C3-C8alkylene chain, where one carbon atom is replaced by O, S, S(O) or SO2;
- R10 is hydrogen, cyano, C1-C8alkyl or C1-C8alkyl substituted by one to three R6a, C1-C8haloalkyl or C1-C8haloalkyl substituted by one to three R6a, C3-C8cycloalkyl or C3-C8cycloalkyl substituted by one to three R6b, C3-C8cycloalkyl where one carbon atom is replaced by O, S, S(O) or SO2, or C3-C8cycloalkyl-C1-C8alkyl, C3-C8cycloalkyl-C1-C8alkyl where one carbon atom in the cycloalkyl group is replaced by O, S, S(O) or SO2, or C3-C8cycloalkyl-C1-C8haloalkyl, C2-C8alkenyl or C2-C8alkenyl substituted by one to three R6a, C2-C8haloalkenyl or C2-C8haloalkenyl substituted by one to three R6a, C2-C8alkynyl, C2-C8haloalkynyl, phenyl, phenyl substituted by one to three R7, phenyl-C1-C4alkyl, phenyl-C1-C4alkyl wherein the phenyl moiety is substituted by one to three R7, 5-6 membered heteroaryl, 5-6 membered heteroaryl substituted by one to three R7, 5-6 membered heteroaryl-C1-C4alkyl or 5-6 membered heteroaryl-C1-C4alky 1 wherein the heteroaryl moiety is substituted by one to three R7;
- or an agrochemically acceptable salt, tautomer or N-oxide thereof.
14 more elements
Dependencies are inferred from the claim text.