Self-releasing in-mold coating (imc) for coating substrates

A composition comprising

• (a) at least one solvent L,
• (b) at least one compound of the general formula (I)
• R1—(C═O)r—O—(AO)s—R2 (I)
• in which R1 is a saturated or unsaturated, aliphatic hydrocarbon radical having 6 to 30 carbon atoms,
• R2 is H, a PO(OH)2 radical, or the optionally partially phosphated radical of a monosaccharide or disaccharide, or the optionally partially phosphated radical of an alditol,
• AO stands for one or more alkylene oxide radicals selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide,
• r is 0 or 1, and s is 0 to 30;
• (c) optionally at least one polyether-modified alkylpolysiloxane,
• (d) at least one polysiloxane of the general formula (II)
• R3—Si(R4)2—[O—Si(R4)(R5)]a—[O—Si(R4)2]b—O—Si(R4)2—R3 (II),
• in which
• R3 and R4, in each case independently of one another, are a methyl group or a (HO—CH2)2—C(CH2—CH3)—CH2—O—(CH2)3—* radical,
• R5 is a methyl group,
• a is 0 or 1 to 10, and
• b is 3 to 30;
• and
• (e) optionally at least one binder B.