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US 2022/0010039 A1Published application
Transition Metal Compound for a Catalyst for Olefin Polymerization and Catalyst for Olefin Polymerization Comprising the Same
AssigneeHanwha Solutions Corporation
InventorsSeongYeon PARK, Wook JEONG, Lanhua PIAO, HyunSeung LEE
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Abstract
The present invention relates to a transition metal compound for a catalyst for olefin polymerization and to a catalyst for olefin polymerization comprising the same. Specifically, the present invention relates to a transition metal compound for an olefin polymerization catalyst in which an allyltrimethylsilane substituent is introduced into the cyclopentadienyl group and to a catalyst for olefin polymerization comprising the same.
Claims12
A transition metal compound represented by Formula 1:
- in Formula 1, n is each independently an integer of 1 to 20,
- M is titanium (Ti), zirconium (Zr), or hafnium (Hf),
- X is each independently halogen, C1-20 alkyl, C2-20 alkenyl, C2-20 alkynyl, C6-20 aryl, C1-20 alkyl C6-20 aryl, C6-20 aryl C1-20 alkyl, C1-20 alkylamido, C6-20 arylamido, or C1-20 alkylidene,
- R1 to R4 and R5 to R8 are each independently hydrogen, substituted or unsubstituted C1-20 alkyl, substituted or unsubstituted C2-20 alkenyl, substituted or unsubstituted C6-20 aryl, substituted or unsubstituted C1-20 alkyl C6-20 aryl, substituted or unsubstituted C6-20 aryl C1-20 alkyl, substituted or unsubstituted C1-20 heteroalkyl, substituted or unsubstituted C3-20 heteroaryl, substituted or unsubstituted C1-20 alkylamido, substituted or unsubstituted C6-20 arylamido, substituted or unsubstituted C1-20 alkylidene, or substituted or unsubstituted C1-20 silyl, and
- R9 to R11 and R12 to R14 are each independently substituted or unsubstituted C1-20 alkyl, substituted or unsubstituted C2-20 alkenyl, substituted or unsubstituted C6-20 aryl, substituted or unsubstituted C1-20 alkyl C6-20 aryl, substituted or unsubstituted C6-20 aryl C1-20 alkyl, substituted or unsubstituted C1-20 heteroalkyl, substituted or unsubstituted C3-20 heteroaryl, substituted or unsubstituted C1-20 alkylamido, substituted or unsubstituted C6-20 arylamido, substituted or unsubstituted C1-20 alkylidene, or substituted or unsubstituted C1-20 silyl,
- wherein R1 to R4 and R5 to R8 are each independently capable of being linked to adjacent groups to form a substituted or unsubstituted saturated or unsaturated C4-20 ring.
3 more elements
Dependencies are inferred from the claim text.