Multiphase particle, manufacturing process and use thereof
AssigneesChina Petroleum & Chemical Corporation, Petroleum Engineering Research Institute, Sinopec
InventorsXuepeng LIU, Wei LIU, Shiming ZHOU, Shidong DING, Qian TAO, Qichun WANG
Life of this patent
Estimating the term…
Abstract
A multiphase particle has a multiphase structure comprising a first phase and a second phase and has an average particle size of 0.1-100 mm. The multiphase particle has a high bulk strength and a good interface binding power with the hardened cement and is particularly suitable for the toughening application of the hardened cement.
Claims18
A multiphase particle, having a multiphase structure comprising (preferably consisting of) a first phase and a second phase, wherein the multiphase structure has, at least in part, a morphology (1):
- the first phase is a continuous phase having, at least in part, a porous structure, the second phase is a dispersed phase, wherein at least one (preferably 50% or more, 60% or more, 80% or more, 90% or more of the total or substantially all) of the second phases has a substantially spherical shape (referred to as a spherical second phase) and at least one (preferably 50% or more, 60% or more, 80% or more, 90% or more of the total or substantially all) of the spherical second phases is located within pores (in particular substantially circular pores) of the porous structure of the first phase, or the multiphase structure has, at least in part, a morphology (2):
- the second phase is a continuous phase (e.g. having a loose structure or an amorphous structure), the first phase is a dispersed phase, wherein at least one (preferably 50% or more, 60% or more, 80% or more, 90% or more of the total or substantially all) of the first phase has a substantially columnar shape (e.g. at least one columnar shape selected from a cylinder shape and a prism shape) (referred to as a columnar first phase), or the multiphase structure has, at least in part, a morphology (3):
- a combined morphology of the morphology (1) and the morphology (2), and the average particle size of the multiphase particle is at least 0.1 mm (preferably at least 0.2 mm, at least 0.35 mm, at least 0.5 mm, at least 0.75 mm, or at least 0.8 mm), and at most 100 mm (preferably at most 50 mm, at most 20 mm, at most 10 mm, at most 5 mm, at most 2 mm, at most 1.2 mm, or at most 1.0 mm).
A manufacturing process for a multiphase particle, comprising at least the following steps:
- A reaction step:
- reacting at least one polyfunctional organic monomer (for example an organic compound having two or more isocyanate (—NCO) groups per molecule, especially for example at least one selected from a polyisocyanate, a polyurethane prepolymer and a polyurea prepolymer, especially at least one selected from a C4+ aliphatic polyisocyanate, a C4+ cycloaliphatic polyisocyanate, an aromatic polyisocyanate, a polyurethane prepolymer derived from at least one of these polyisocyanates, and a polyurea prepolymer derived from at least one of these polyisocyanates, especially at least one selected from an C4+ aliphatic diisocyanate, a C4+ cycloaliphatic diisocyanate, an aromatic diisocyanate, a polyurethane prepolymer derived from at least one of these diisocyanates, and a polyurea prepolymer derived from at least one of these diisocyanates, especially at least one selected from toluene diisocyanate, 4,4′-diphenylmethane diisocyanate, 4,4′-dicyclohexylmethane diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, 1,4-cyclohexane diisocyanate, naphthalene diisocyanate, a polyurethane prepolymer derived from at least one of these diisocyanates, and a polyurea prepolymer derived from at least one of these diisocyanates, especially at least one selected from 4,4′-diphenylmethane diisocyanate, a polyurethane prepolymer derived from the diisocyanate, and a polyurea prepolymer derived from the diisocyanate, especially a polyurethane prepolymer derived from 4,4′-diphenylmethane diisocyanate) and at least one polyfunctional inorganic monomer exhibiting a chemical reaction activity to the polyfunctional organic monomer (for example an inorganic compound having 2 or more-OH groups per molecule and/or a precursor thereof, especially for example at least one selected from a silica sol, an alumina sol, a zirconium sol, a titanium sol, a silicate ester, an aqueous silicate ester solution, a silicate salt, an aqueous silicate salt solution, an aluminate salt, an aqueous aluminate salt solution, a titanate ester, an aqueous titanate ester solution, a zirconate ester, an aqueous zirconate ester solution and water, especially at least one selected from silica sol and an aqueous silicate salt solution, especially an aqueous silicate salt solution, for example water glass) in presence of optionally at least one inorganic nanoparticle (for example a nanoparticle consisting essentially of an inorganic substance, for example at least one selected from calcium carbonate nanoparticle, silica nanoparticle and hydrotalcite nanoparticle, especially calcium carbonate nanoparticle, more especially heavy calcium carbonate nanoparticle) and optionally at least one polyfunctional reactive hydrogen organic compound (for example an organic compound containing two or more reactive hydrogen atoms per molecule, especially for example at least one selected from a polyamine, a polycarboxylic acid, a polyphenol, a polythiol and a polyol, especially at least one selected from a polyether polyol and a polyester polyol, especially a polyether polyol, preferably the polyether polyol has a number-average molecular weight of 500-8000, preferably 1000-6000 and a hydroxy functionality of 2-3, in particular preferably the polyether polyol is at least one selected from a polytetrahydrofuran diol and a polypropylene oxide polyol, in particular preferably a polypropylene oxide polyol or a polypropylene oxide glycol, especially at least one selected from polypropylene oxide glycol 1000, polypropylene oxide glycol 2000, polypropylene oxide glycol 3000, polypropylene oxide glycol 5000 and polypropylene oxide glycol 6000), in presence of a catalyst (for example at least one selected from a carboxylate salt, a metal alkyl compound, a quaternary ammonium salt and a tertiary amine, especially at least one selected from stannous octoate, potassium carboxylate and dibutyl tin dilaurate) or in absence of a catalyst to obtain an organic-inorganic composite material in a solid form, and
- A comminution step:
- comminuting the organic-inorganic composite material to obtain the multiphase particle, wherein the average particle size of the multiphase particle is at least 0.1 mm (preferably at least 0.2 mm, at least 0.35 mm, at least 0.5 mm, at least 0.75 mm or at least 0.8 mm), at most 100 mm (preferably at most 50 mm, at most 20 mm, at most 10 mm, at most 5 mm, at most 2 mm, at most 1.2 mm or at most 1.0 mm).
Dependencies are inferred from the claim text.