Method of preparing a mesoporous carbon composite material
AssigneeTechnische UniversitäT Berlin
InventorsDenis BERNSMEIER, Ralph KRÄHNERT, René SACHSE
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Abstract
A method of preparing a mesoporous carbon composite material having a mesoporous carbon phase and preformed metal nanoparticles located within the mesoporous carbon phase. The present invention also relates to a mesoporous carbon composite material and to a substrate having a film of such mesoporous carbon composite material.
Claims21
-21. (canceled)
A method of preparing a mesoporous carbon composite material comprising a mesoporous carbon phase and preformed metal nanoparticles located within the mesoporous carbon phase, the method comprising the steps:
- a) providing a solution of carbon composite precursors, the solution of carbon composite precursors comprising a structure directing agent capable of forming micelles or lamellar structures, one or several poylmerizable carbon precursor components and a first solvent;
- b) inducing the solution of carbon composite precursors to polymerize to form a dispersion of polymer in the first solvent, and separating the polymer from the first solvent;
- c) providing preformed stabilized metal nanoparticles;
- d) mixing the polymer and the preformed stabilized metal nanoparticles, wherein during the mixing either the polymer or the preformed stabilized metal nanoparticles or both are dispersed in a second solvent;
- e) stabilizing the mixture of step d) by subjecting it to a stabilization heat treatment in the range of from 80° C. to 120° C., preferably 90° C. to 110° C., more preferably around 100° C.;
- and
- f) subjecting the product of step e) to a carbonization heat treatment in the range of from 500° C. to 1000° C., preferably from 600° C. to 800° C.
A mesoporous carbon composite material comprising a mesoporous carbon phase and preformed metal nanoparticles located within the mesoporous carbon phase, wherein the mesoporous carbon phase has pores with an average size in the range of from 2 nm to 50 nm,
- wherein the preformed metal nanoparticles are not preformed monometallic Pt-nanoparticles.
Dependencies are inferred from the claim text.