Lithium solid electrolyte and method of manufacture thereof
AssigneesSamsung Electronics Co., Ltd., Massachusetts Institute of Technology
InventorsYuntong Zhu, Won Seok Chang, Jennifer Rupp, Lincoln Miara
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Abstract
A method of manufacturing a lithium solid electrolyte, the method including: providing a composition including a lithium precursor, a lanthanum precursor, and a zirconium precursor; disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film; and heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.
Claims25
A method of manufacturing a lithium solid electrolyte, the method comprising:
- providing a composition comprising a lithium precursor, a lanthanum precursor, and a zirconium precursor;
- disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film;
- and
- heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.
A lithium solid electrolyte of Formula 1
- Li(7.2-2x-3y)AxMyLa3Zr2O12 (1)
- wherein A is Ca or Mg, M is Al or Ga, and wherein 0≤x≤0.5 and 0≤y≤0.5, and having a having a local stress of 10 megaPascals to 10 gigaPascals, when determined by multi-beam optical sensing.
Dependencies are inferred from the claim text.