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US 2020/0392292 A1Published application
Resin composition, method for producing resin composition, film formation method, and cured product
AssigneeTokyo Ohka Kogyo Co., Ltd.
InventorsKunihiro NODA, Hiroki CHISAKA, Kazuya SOMEYA, Dai SHIOTA
Life of this patent
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Abstract
A resin composition including a silicon-containing resin component and a solvent, the silicon-containing resin component includes (I) mentioned below, the solvent including at least one of a terpene compound having at least one of a hydroxy group and an acetoxy group, and a cyclic skeleton-containing acetate compound (excluding the terpene compound): (I) a polysilane-polysiloxane resin having a polysilane structure and a polysiloxane structure.
Claims6
A resin composition comprising a silicon-containing resin component and a solvent, wherein:
- the silicon-containing resin component comprises (I):
- (I) a polysilane-polysiloxane resin having a polysilane structure (I-1) and a polysiloxane structure (I-2),
- the solvent comprises at least one solvent selected from the group consisting of a terpene compound having at least one group selected from the group consisting of a hydroxy group and an acetoxy group, and a cyclic skeleton-containing acetate compound (excluding the terpene compound),
- wherein the polysiloxane structure (I-2) comprises a hydrolyzed and condensed structure of at least one silicon compound selected from the group consisting of silicon compounds represented by the following general formulas (A-1-1) to (A-1-4):
- R1R2R3SiX1 (A-1-1)
- R4R6SiX22 (A-1-2)
- R6SiX33 (A-1-3)
- SiX44 (A-1-4)
- wherein X1 to X4 are each independently a hydrolyzable group, and wherein R1, R2, R3, R4, R5, and R6 are each independently a hydrogen atom or an organic group, and hydrogen atoms in the organic group may be substituted with a halogen atom,
- wherein the polysilane structure (I-1) comprises a structure corresponding to at least one selected from the group consisting of polysilane compounds represented by the following general formulas (A-2-1) and (A-2-2):
- (R7R8R9Si)a1(R10R11Si)a2(R12Si)a3(Si)a4 (A-2-1)
- wherein R7, R8, R9, R10, R11 and R12 are each independently a hydrogen atom, a hydroxyl group, or an organic group, and a1, a2, a3 and a4 are each independently a molar fraction, a1+a2+a3+a4=1, 0≤a1≤1, 0≤a2≤1, 0≤a3≤1 and 0≤a4≤1,
- wherein Ra1 and Ra2 each independently represents a hydrogen atom, a hydroxyl group, or an organic group, and n represents an integer of 5 to 20, and wherein (I) the polysilane-polysiloxane resin comprises at least one selected from the group consisting of a structure represented by the following general formulas (H1), (H2) and (H3):
- A1-A2O—Psi-OA2-A1 (H 1)
- A1-A2O—Psi-OH (H 2)
- A1-A2O—Psi-OA2-A1-A2O—Psi-OA2-A1 (H 3)
- wherein in the general formulas (H1) and (H2), A1 each independently represents a polysiloxane structure which includes at least one of structures represented by the general formulas (A1) shown below, and also includes at least one leftmost structure,
- in the general formulas (H3), A1, -A2O—, —OA2-, and Psi are the same as defined in the general formula (H1), and
- A2O— each independently represents a linking group which is any one of structures represented by the general formula (A2) shown below, in the general formulas (H1), —OA2- represents an —OSi— structure in which the order of bonding a main chain —SiO— in the general formula (A1) shown below is reversed, Psi represents a polysilane structure (I-1):
- wherein in the general formulas (A1) and (A2), R1, R2, R3, R4, R5, and R6 are each independently a hydrogen atom or an organic group, and hydrogen atoms in the organic group may be substituted with a halogen atom.
17 more elements
Dependencies are inferred from the claim text.