Sulfate scale inhibition in high pressure and high temperature applications
AssigneeBl Technologies, Inc.
InventorsCaroline Chihyu Sui, Claudia C. Pierce
Life of this patent
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Abstract
Methods are provided to inhibit scale formation in oil or gas production systems. In one embodiment, the scale inhibiting treatment comprises: A) an AAA terpolymer and B) a phosphonate. The treatment can be added to these systems in the well area itself, to the well annulus and its associated tubes, casings, etc., to the oil or gas bearing subterranean formation, to injection conduits for injecting steam or fracking fluid to the subterranean formation, to the produced water or to equipment in fluid flow contact with the produced water.
Claims23
A method of inhibiting scale formation in an oil or gas production system comprising adding to said system a scale inhibiting treatment comprising:
- (A) a water soluble or dispersible polymer having the formula I
- wherein E is the repeat unit remaining after polymerization of an ethylenically unsaturated compound;
- R1 is H or lower alkyl (C1-C4);
- or CH2—CH2—CH2;
- f is an integer of about 1-100, preferably from about 1-20, X and A are independently selected and are an anionic group selected from OSO3, SO3, PO3, OPO3, or COO;
- G and Z are independently selected and are chosen from H or a cationic group such as Na, K, or NH4;
- R3 is H or lower alkyl (C1-C4), and R4 is a hydroxyl substituted alkylene radical having from 1 to about 6 carbon atoms;
- subscripts c, d, and e represent the molar amounts of the monomer repeat units in the polymer and wherein c is present in an amount of 1-80, d is present in an amount of 0-30, and e is present in an amount of 0-30, with the proviso that at least one of d and e must be present and the sum of c+d+e=100;
- and
- (B) phosphonate.
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Dependencies are inferred from the claim text.