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US 2019/0375912 A1Published application
Modified Polymerization Initiator and Modified Conjugated Diene-Based Polymer Including Functional Group Derived Therefrom
AssigneeLG Chem, Ltd.
InventorsJung Yong Lee, Jae Hoon Choe, Dong Cheol Choe, Jong Young Choi, Won Jae Lee, Hyeon Hui Kim
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Abstract
The present invention relates to a modified polymerization initiator for a conjugated diene-based polymer, and a modified conjugated diene-based polymer including a functional group derived from the modified polymerization initiator.
Claims7
A modified polymerization initiator comprising:
- one or more units derived from a compound represented by the following Formula 1, and a unit derived from a compound represented by the following Formula 2:
- in Formula 1,
- X is —NRaRb, —ORc, or —SRd, and
- Ra to Rd are each independently an alkyl group of 1 to 30 carbon atoms, an alkenyl group of 2 to 30 carbon atoms, an alkynyl group of 2 to 30 carbon atoms, a cycloalkyl group of 3 to 30 carbon atoms, an aryl group of 6 to 30 carbon atoms, a heteroalkyl group of 1 to 30 carbon atoms, a heteroalkenyl group of 2 to 30 carbon atoms, a heteroalkynyl group of 2 to 30 carbon atoms, a heterocycloalkyl group of 2 to 30 carbon atoms, or a heteroaryl group of 3 to 30 carbon atoms, where each of Ra to Rd is unsubstituted or substituted with a substituent comprising one or more heteroatoms selected from N, O, S, Si and F atoms, and Ra and Rb may be connected with each other to form an aliphatic hydrocarbon ring of 5 to 20 carbon atoms, an aromatic hydrocarbon ring of 6 to 20 carbon atoms, or a heterocycle of 3 to 20 carbon atoms, which are unsubstituted or substituted with an alkyl group of 1 to 30 carbon atoms,
- M-R1 [Formula 2]
- in Formula 2,
- M is an alkali metal, and
- R1 is hydrogen, an alkyl group of 1 to 30 carbon atoms, an alkenyl group of 2 to 30 carbon atoms, an alkynyl group of 2 to 30 carbon atoms, a cycloalkyl group of 5 to 30 carbon atoms, or an aryl group of 6 to 30 carbon atoms.
5 more elements
Dependencies are inferred from the claim text.