Aromatic amine derivatives, preparation methods therefor, and uses thereof

An aromatic amine derivative as shown in general formula (I):

• wherein
• R1, R2, R3, R4, R5, R6, R7 or R8 is the same or different from each other, and is each independently selected from the group consisting of:
• H, a linear alkyl containing 1 to 20 carbon atoms, an alkoxy containing 1 to 20 carbon atoms, a thioalkoxy containing 1 to 20 carbon atoms, a branched or cyclic alkyl containing 3 to 20 carbon atoms, a substituted or unsubstituted silyl group, a substituted keto group containing 1 to 20 carbon atoms, an alkoxycarbonyl group containing 2 to 20 carbon atoms, an aryloxycarbonyl group containing 7 to 20 carbon atoms, a cyano group, a carbamoyl group, a haloformyl group, a formyl group, an isocyano group, an isocyanate group, a thiocyanate group or an isothiocyanate group, a hydroxyl group, a nitro group, CF3, Cl, Br, F, a crosslinkable group, a substituted or unsubstituted aromatic ring system containing 5 to 40 ring atoms or substituted or unsubstituted heteroaromatic ring system containing 5 to 40 ring atoms, and an aryloxy group containing 5 to 40 ring atoms or heteroaryloxy group containing 5 to 40 ring atoms;
• one or more groups of the R1, R2, R3, R4, R5, R6, R7 or R8 can form a monocyclic or polycyclic aliphatic or aromatic ring system with each other and/or with a ring bonded to the group;
• and, one or more hydrogen atoms of the R1, R2, R3, R4, R5, R6, R7 or R8 can be substituted by deuterium atoms;
• Ar1, Ar2, Ar3 or Ar4 is the same or different from each other;
• at least one of the Ar1, Ar2, Ar3 or Ar4 is a group represented by general formula (II), and the others are each independently selected from the group consisting of:
• a substituted or unsubstituted aromatic ring system containing 5 to 40 ring atoms or substituted or unsubstituted heteroaromatic ring system containing 5 to 40 ring atoms, and an aryloxy group containing 5 to 40 ring atoms or heteroaryloxy group containing 5 to 40 ring atoms;
• wherein one or more groups of the Ar1, Ar2, Ar3 or Ar4 can form a polycyclic aliphatic or aromatic ring systems with each other and/or with a ring bonded to the group;
• and, one or more hydrogen atoms of the Ar1, Ar2, Ar3 or Ar4 can be substituted by deuterium atoms;
• the general formula (II) is:
• wherein
• R9, R10, R11, R12 or R13 is the same or different from each other, and is each independently selected from the group consisting of:
• H, a linear alkyl containing 1 to 20 carbon atoms, an alkoxy containing 1 to 20 carbon atoms, a thioalkoxy containing 1 to 20 carbon atoms, a branched or cyclic alkyl containing 3 to 20 carbon atoms, a substituted or unsubstituted silyl group, a substituted keto group containing 1 to 20 carbon atoms, an alkoxycarbonyl group containing 2 to 20 carbon atoms, an aryloxycarbonyl group containing 7 to 20 carbon atoms, a cyano group, an carbamoyl group, a haloformyl group, a formyl group, an isocyano group, an isocyanate group, a thiocyanate or isothiocyanate group, a hydroxyl group, a nitro group, CF3, Cl, Br, F, a crosslinkable group, a substituted or unsubstituted aromatic ring system containing 5 to 40 ring atoms or substituted or unsubstituted heteroaromatic ring system containing 5 to 40 ring atoms, and an aryloxy group containing 5 to 40 ring atoms or heteroaryloxy group containing 5 to 40 ring atoms;
• one or more groups of the R9, R10, R11, R12 or R13 can form a monocyclic or polycyclic, aliphatic or aromatic ring system with each other and/or with a ring bonded to the group;
• Ar5 or Ar6 is the same or different, and is each independently selected from the group consisting of:
• a linear alkyl containing 1 to 20 carbon atoms, an alkoxy containing 1 to 20 carbon atoms, a thioalkoxy containing 1 to 20 carbon atoms, a branched or cyclic alkyl containing 3 to 20 carbon atoms, a substituted or unsubstituted silyl group, a substituted keto group containing 1 to 20 carbon atoms, an alkoxycarbonyl group containing 2 to 20 carbon atoms, an aryloxycarbonyl group containing 7 to 20 carbon atom, a cyano group, a carbamoyl group, a haloformyl group, a formyl group, an isocyano group, an isocyanate group, a thiocyanate or isothiocyanate group, a hydroxyl group, a nitro group, CF3, Cl, Br, F, a crosslinkable group, a substituted or unsubstituted aromatic ring system containing 5 to 40 ring atoms or substituted or unsubstituted heteroaromatic ring system containing 5 to 40 ring atoms, and an aryloxy group containing 5 to 40 ring atoms or heteroaryloxy group containing 5 to 40 ring atoms;
• one or more groups of the Ar5, Ar6 can form a polycyclic aliphatic or aromatic ring system with each other and/or with a ring bonded to the group;
• and, one or more hydrogen atoms of the R9, R10, R11, R12, R13, Ar5 or Ar6 can be substituted by deuterium atoms;
• and
• the dotted line represents a single bond linked to the general formula (I).