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US 2019/0292482 A1Published application
Lubricating oil composition, lubrication method, and gear
AssigneeIdemitsu Kosan Co., Ltd.
InventorsYasuhito NAKAHARA, Masato YOKOMIZO, Hideki KAMANO
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Abstract
Provided are a lubricating oil composition excellent in anti-seizing properties and ant-wear properties, containing a base oil containing at least a mineral oil and a sulfur- and phosphorus-containing anti-wear agent, a mass ratio (S/P ratio) of a sulfur atom and a phosphorus atom contained in the composition being 7.5 or more and 16 or less; and a lubrication method and a gear each using the same.
Claims13
1:
- A lubricating oil composition, comprising:
- a base oil containing at least a mineral oil, and
- a sulfur- and phosphorus-containing anti-wear agent,
- wherein a mass ratio (S/P ratio) of a sulfur atom and a phosphorus atom contained in the composition is 7.5 or more and 16 or less.
1 more element
2:
- The lubricating oil composition according to claim 1, further comprising:
- at least one selected from the group consisting of a phosphoric acid ester, an amine salt thereof, and a polysulfide.
3:
- The lubricating oil composition according to claim 1, wherein:
- the sulfur- and phosphorus-containing anti-wear agent is at least one selected from the group consisting of a compound represented by formula (1) and a compound represented by formula (2):
- R11 is a hydrogen atom, a hydroxy group, or a mercapto group;
- R12 and R13 are each independently a hydroxy group, a mercapto group, —X12—R14, or —X13—R15—X14—R16, provided that at least one of R12 and R13 is —X12—R14 or —X13—R15—X14—R16;
- X11, X12, X13, and X14 are each independently an oxygen atom or a sulfur atom, provided that at least one of X11, X12, X13, and X14 is a sulfur atom;
- R14 and R16 are each independently a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- R15 is a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- R21, R22, and R24 are each independently a hydrogen atom or a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- R23 is a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- R25 is an organic group or a nitrogen-containing group;
- and
- X21, X22, X23, and X24 are each independently an oxygen atom or a sulfur atom, provided that at least one of X21, X22, X23, and X24 is a sulfur atom.
9 more elements
4:
- The lubricating oil composition according to claim 3, wherein:
- R11 is a hydrogen atom or a hydroxy group;
- R12 and R13 are each independently a hydroxy group or —X13—R15—X14—R16, provided that at least one of R12 and R13 is —X13—R15—X14—R16;
- R15 is a hydrocarbon group having 1 or more and 4 or less carbon atoms;
- R16 is a hydrocarbon group having 6 or more and 10 or less carbon atoms;
- X11 is an oxygen atom;
- and
- X13 and X14 are each independently an oxygen atom or a sulfur atom, provided that at least one of X13 and X14 is a sulfur atom.
5 more elements
5:
- The lubricating oil composition according to claim 3, wherein:
- R21 and R22 are each independently a hydrocarbon group having 1 or more and 6 or less carbon atoms;
- R23 is a hydrocarbon group having 1 or more and 4 or less carbon atoms;
- R24 is a hydrogen atom or a hydrocarbon group having 1 or more and 4 or less carbon atoms;
- R25 is a carboxy group, an acyloxy group having an alkyl group having 1 or more and 4 or less carbon atoms, or an alkyl ester group having an alkyl group having 1 or more and 4 or less carbon atoms;
- X21 and X22 are each an oxygen atom;
- and
- X23 and X24 are each a sulfur atom.
5 more elements
6:
- The lubricating oil composition according to claim 2, wherein:
- the lubricating oil composition comprises at least one phosphoric acid ester selected from the group consisting of a compound represented by formula (3) and a compound represented by formula (4):
- R31 is a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- m31 is 1, 2, or 3;
- in the case where m31 is 2 or 3, plural R31's may be the same as or different from each other;
- R41 is a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- m41 is 1 or 2;
- and
- in the case where m41 is 2, plural R41's may be the same as or different from each other.
6 more elements
7:
- The lubricating oil composition according to claim 2, wherein:
- the lubricating oil composition comprising at least one polysulfide selected from the group consisting of a compound represented by formula (5) and a compound represented by formula (6):
- wherein, in the general formula (5),
- R51 and R52 are each independently a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- m51 is an integer of 2 or more and 10 or less;
- R61 and R63 are each independently a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- R62 is a hydrocarbon group having 1 or more and 24 or less carbon atoms;
- m61 and m62 are each an integer of 1 or more and 10 or less;
- and
- p61 is an integer of 1 or more and 8 or less.
7 more elements
8:
- The lubricating oil composition according to claim 1, further comprising:
- a succinimide-based dispersant.
9:
- The lubricating oil composition according to claim 1, which has a 100° C. kinematic viscosity of 8 mm2/s or more and 12 mm2/s or less.
10:
- The lubricating oil composition according to claim 1, which is adapted to function as a lubricating oil composition for gear oils.
11:
- A lubrication method, comprising lubricating an article or a substance with a lubricating oil composition comprising:
- a base oil containing at least a mineral oil;
- and
- a sulfur- and phosphorus-containing anti-wear agent,
- wherein a mass ratio (S/P ratio) of a sulfur atom and a phosphorus atom contained in the composition is 7.5 or more and 16 or less.
2 more elements
12:
- The lubrication method according to claim 11, comprising lubricating gears with the lubricating oil composition.
13:
- A gear, comprising a lubricating oil composition comprising:
- a base oil containing at least a mineral oil;
- and
- a sulfur- and phosphorus-containing anti-wear agent,
- wherein a mass ratio (S/P ratio) of a sulfur atom and a phosphorus atom contained in the composition is 7.5 or more and 16 or less.
2 more elements