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OwnerVirginia M. Reiner, Nabila Brabez +2inventors
InventorsVirginia M. Reiner, Nabila Brabez, Ross Mabon, Ashley M. Wittrig
Estimating the term…
Technical lignin compositions and pyrolysis methods for forming such technical lignin compositions from pyrolyzed biomass are provided. The technical lignin compositions can include at least about 50 wt % phenolic polymers and/or at least about 75 wt % combined phenolic monomers and phenolic polymers. In some aspects, less than about 50 wt % of the linkages between benzylic units in the phenolic polymers and/or in the composition can correspond to β-O-4 linkages. At least about 50 wt % of the hydroxyl groups in the composition can correspond to phenolic hydroxyl groups. At least about 60 wt % of the phenolic hydroxyl groups and/or phenolic ether groups can correspond to phenolic hydroxyl groups and/or phenolic ether groups in an ortho position relative to at least one substituent.
-21. (canceled)
The use of a technical lignin composition as an antioxidant additive for a mineral synthetic grease or mineral lubricant base oil, the lignin composition comprising:
The use of claim 1, wherein the combined phenolic monomers and phenolic polymers comprise an effective hydrogen index of about 1.0 or less.
The use of claim 1, wherein at least about 60% of the phenolic hydroxyl groups comprise a phenolic hydroxyl group in an ortho position relative to two substituents.
The use of claim 1, wherein the at least about 60% of the phenolic hydroxyl groups comprise phenolic hydroxyl groups in an ortho position relative to a methyl substituent, an ethyl substituent, a methoxy substituent, a hydroxyl substituent, an ether substituent, or a combination thereof.
The use of claim 1, wherein about 30 wt % or less of the phenolic polymers comprise natural lignins.
The use of claim 1, wherein at least about 60 wt % of the phenolic polymers comprise technical lignins.
The use of claim 1, wherein at least about 60 wt % of the phenolic polymers comprise pyrolytic lignins.
The use of claim 1, wherein about 50% or less of linkages connecting benzylic units in the phenolic polymers comprise an ether group or a carbonyl group.
The use of claim 1, wherein the composition comprises about 5.0 wt % or less of sugars.
The use of a technical lignin composition as an antioxidant additive for a mineral synthetic grease or mineral lubricant base oil, the lignin composition comprising:
The use of claim 10, wherein the composition comprises an effective hydrogen index of about 1.0 or less.
The use of claim 10, wherein at least about 60% of the combined phenolic ether groups and phenolic hydroxyl groups comprise a phenolic ether group or a phenolic hydroxyl group in an ortho position relative to two substituents.
The use of claim 10, wherein the at least about 60% of the phenolic hydroxyl groups comprise phenolic hydroxyl groups in an ortho position relative to a methyl substituent, an ethyl substituent, a methoxy substituent, a hydroxyl substituent, an ether substituent, or a combination thereof.
The use of claim 10, wherein about 50% or less of linkages connecting benzylic units in the phenolic polymers comprise an ether group or a carbonyl group.
Dependencies are inferred from the claim text.