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US 2018/0316000 A1Published application
Positive electrode active material, lithium ion secondary battery, and method of producing positive electrode active material
AssigneesToyota Jidosha Kabushiki Kaisha, Sumitomo Metal Mining Co., Ltd.
InventorsRyuta Sugiura, Satoshi Kanada, Tetsutaro Hayashi, Taira Aida
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Abstract
A positive electrode active material includes secondary particles. The secondary particles include a plurality of primary particles. The primary particles include a lithium-containing composite metal oxide. Inside the secondary particles, an electron conducting oxide is disposed at at least a part of a grain boundary between the primary particles. The electron conducting oxide has a perovskite structure.
Claims10
A positive electrode active material comprising:
- secondary particles,
- wherein the secondary particles include a plurality of primary particles, the primary particles are a lithium-containing composite metal oxide, inside the secondary particles, an electron conducting oxide is disposed at at least a part of a grain boundary between the primary particles, and the electron conducting oxide has a perovskite structure and is represented by Formula (I):
- ACox1Mx2O3, wherein in the formula, A is at least one of La and Sr, M is at least one of Mn and Ni, and x1 and x2 satisfy 0<x1≤1, 0≤x2≤1, and 0.6≤x1+x2≤1.
A method of producing a positive electrode active material comprising:
- preparing a precursor using a coprecipitation method;
- preparing a mixture by mixing the precursor and a lithium compound;
- preparing a sintered product by heating the mixture;
- and
- disintegrating the sintered product to produce the positive electrode active material,
- wherein the precursor includes secondary particles, the secondary particles include a plurality of primary particles, and the primary particles are a composite metal hydroxide,
- wherein, when the mixture is heated, the primary particles become a lithium-containing composite metal oxide, and an electron conducting oxide is precipitated at at least a part of a grain boundary between the primary particles, and
- wherein the electron conducting oxide has a perovskite structure that is represented by Formula (I):
- ACox1Mx2O3, wherein in the formula, A is at least one of La and Sr, M is at least one of Mn and Ni, and x1 and x2 satisfy 0<x1≤1, 0≤x2≤1, and 0.6≤x1+x2≤1.
6 more elements
Dependencies are inferred from the claim text.