Composition
AssigneeSumitomo Chemical Company, Limited
InventorsNoriyuki HIDA, Haruki OKAWA
Life of this patent
Estimating the term…
Abstract
A composition is provided which contains a compound represented by Formula (1) below and a polymerizable smectic liquid crystal compound: In Formula (1), R1 represents a hydrogen atom or a C1-C20 alkyl group; R2 through R4 each independently represent a C1-C4 alkyl group; n, p, and q are each independently an integer of 0 to 2; and R5 is (i) a nitrogen-containing saturated heterocyclic group which is a 6-membered ring and in which N is bonded to a phenylene group, or (ii) a group in which N is bonded to at least one C1-C10 alkyl group.
Claims19
A composition comprising:
- a compound represented by Formula (1) below;
- and
- a polymerizable smectic liquid crystal compound,
- where:
- R1 represents a hydrogen atom, a C1-C20 alkyl group, a C1-C20 alkoxy group, a C1-C20 acyl group, a C2-C20 alkoxycarbonyl group, a C1-C20 acyloxy group, or —N(R10)(R11);
- R10 represents a C1-C20 acyl group, a C1-C20 alkylsulfonyl group, or a C6-C20 arylsulfonyl group;
- R11 represents a hydrogen atom or a C1-C20 alkyl group;
- R10 and R11 can bond to each other, and form, with a nitrogen atom to which R10 and R11 bond, a ring including —N—CO— or —N—SO2—;
- at least one hydrogen atom of any of the alkyl group, the alkoxy group, the acyl group, the alkoxycarbonyl group, the acyloxy group, the alkylsulfonyl group, and the arylsulfonyl group can be substituted by a halogen atom, a hydroxy group, an unsubstituted amino group, or a substituted amino group;
- —O— or —NR20— can be inserted between carbon atoms of any of the alkyl group and the alkoxy group;
- R20 represents a hydrogen atom or a C1-C20 alkyl group;
- R2 through R4 are substituents which are not hydrogen atoms and each independently represent a C1-C4 alkyl group, a C1-C4 alkoxy group, a halogen atom, or a cyano group;
- at least one hydrogen atom of any of the alkyl group and the alkoxy group can be substituted by a halogen atom or a hydroxy group;
- n, p, and q are each independently an integer of 0 to 2;
- R5 is selected from the group consisting of Ar1, NHR5a, N(R5b)2, and N(R5a)(R5b);
- Ar1 represents a nitrogen-containing saturated heterocyclic group which is a 6-membered ring and in which (i) N is bonded to a phenylene group and (ii) a γ-position is an oxygen atom or a sulfur atom, and 1 to 6 of hydrogen atoms bonding to a ring of the nitrogen-containing saturated heterocyclic group can be substituted by a C1-C3 alkyl group;
- R5a is (i) a C1-C10 alkyl group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms;
- R5b is (i) a C1-C10 alkyl group in which a hydrogen atom is substituted by at least one hydroxy group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms;
- and
- in the N(R5b)2, R5b are each independent and are mutually identical or differing groups.
A compound represented by Formula (10) below:
- where:
- R40 represents a C1-C20 alkyl group, a C1-C20 alkoxy group, a C1-C20 acyl group, a C2-C20 alkoxycarbonyl group, a C1-C20 acyloxy group, or —N(R10)(R11);
- R10 represents a C1-C20 acyl group, a C1-C20 alkylsulfonyl group, or a C6-C20 arylsulfonyl group;
- R11 represents a hydrogen atom or a C1-C20 alkyl group;
- R10 and R11 can bond to each other, and form, with a nitrogen atom to which R10 and R11 bond, a ring including —N—CO— or —N—SO2—;
- at least one hydrogen atom of any of the alkoxy group, the acyl group, the alkoxycarbonyl group, the acyloxy group, the alkylsulfonyl group, and the arylsulfonyl group can be substituted by a halogen atom, a hydroxy group, an unsubstituted amino group, or a substituted amino group;
- at least one hydrogen atom of the alkyl group can be substituted by a hydroxy group, an unsubstituted amino group, or a substituted amino group;
- —O— or —NR20— can be inserted between carbon atoms of any of the alkyl group and the alkoxy group;
- R20 represents a hydrogen atom or a C1-C20 alkyl group;
- R2 through R4 are substituents which are not hydrogen atoms and each independently represent a C1-C4 alkyl group, a C1-C4 alkoxy group, a halogen atom, or a cyano group;
- at least one hydrogen atom of any of the alkyl group and the alkoxy group can be substituted by a halogen atom or a hydroxy group;
- n, p, and q are each independently an integer of 0 to 2;
- and
- Ar1 represents a nitrogen-containing saturated heterocyclic group which is a 6-membered ring and in which (i) N is bonded to a phenylene group and (ii) a γ-position is an oxygen atom or a sulfur atom, and 1 to 6 of hydrogen atoms bonding to a ring of the nitrogen-containing saturated heterocyclic group can be substituted by a C1-C3 alkyl group.
A compound represented by Formula (11) below:
- where:
- R41 represents a C1-C20 alkyl group, a C1-C20 alkoxy group, a C1-C20 acyl group, a C2-C20 alkoxycarbonyl group, a C1-C20 acyloxy group, or —N(R10)(R11);
- R10 represents a C1-C20 acyl group, a C1-C20 alkylsulfonyl group, or a C6-C20 arylsulfonyl group;
- R11 represents a hydrogen atom or a C1-C20 alkyl group;
- R10 and R11 can bond to each other, and form, with a nitrogen atom to which R10 and R11 bond, a ring including —N—CO— or —N—SO2—;
- at least one hydrogen atom of any of the alkyl group represented by R41 and the alkoxy group represented by R41 is substituted by at least one halogen atom, at least one hydroxy group, at least one unsubstituted amino group, or at least one substituted amino group;
- at least one hydrogen atom of any of the alkyl group represented by R11, the acyl group, the alkoxycarbonyl group, the acyloxy group, the alkylsulfonyl group, and the arylsulfonyl group can be substituted by a halogen atom, a hydroxy group, an unsubstituted amino group, or a substituted amino group;
- —O— or —NR20— can be inserted between carbon atoms of any of the alkyl group and the alkoxy group;
- R20 represents a hydrogen atom or a C1-C20 alkyl group;
- R2 through R4 are substituents which are not hydrogen atoms and each independently represent a C1-C4 alkyl group, a C1-C4 alkoxy group, a halogen atom, or a cyano group;
- at least one hydrogen atom of any of the alkyl group and the alkoxy group can be substituted by a halogen atom or a hydroxy group;
- n, p, and q are each independently an integer of 0 to 2;
- and
- R5a is (i) a C1-C10 alkyl group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms.
A compound represented by Formula (12) below:
- where:
- R42 represents a C1-C20 alkyl group, a C1-C20 alkoxy group, a C1-C20 acyl group, a C2-C20 alkoxycarbonyl group, a C1-C20 acyloxy group, or —N(R10)(R11);
- R10 represents a C1-C20 acyl group, a C1-C20 alkylsulfonyl group, or a C6-C20 arylsulfonyl group;
- R11 represents a hydrogen atom or a C1-C20 alkyl group;
- R10 and R11 can bond to each other, and form, with a nitrogen atom to which R10 and R11 bond, a ring including —N—CO— or —N—SO2—;
- at least one hydrogen atom of any of the alkyl group, the alkoxy group, the acyl group, the alkoxycarbonyl group, the acyloxy group, the alkylsulfonyl group, and the arylsulfonyl group can be substituted by a halogen atom, a hydroxy group, an unsubstituted amino group, or a substituted amino group;
- —O— or —NR20— can be inserted between carbon atoms of any of the alkyl group and the alkoxy group;
- R20 represents a hydrogen atom or a C1-C20 alkyl group;
- R2 through R4 are substituents which are not hydrogen atoms and each independently represent a C1-C4 alkyl group, a C1-C4 alkoxy group, a halogen atom, or a cyano group;
- at least one hydrogen atom of any of the alkyl group and the alkoxy group can be substituted by a halogen atom or a hydroxy group;
- n, p, and q are each independently an integer of 0 to 2;
- R5b is (i) a C1-C10 alkyl group in which a hydrogen atom is substituted by at least one hydroxy group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms;
- and
- in the N(R5b)2, R5b are each independent and are mutually identical or differing groups.
A compound represented by Formula (13) below:
- where:
- R1 represents a hydrogen atom, a C1-C20 alkyl group, a C1-C20 alkoxy group, a C1-C20 acyl group, a C2-C20 alkoxycarbonyl group, a C1-C20 acyloxy group, or —N(R10)(R11);
- R10 represents a C1-C20 acyl group, a C1-C20 alkylsulfonyl group, or a C6-C20 arylsulfonyl group;
- R11 represents a hydrogen atom or a C1-C20 alkyl group;
- R10 and R11 can bond to each other, and form, with a nitrogen atom to which R10 and R11 bond, a ring including —N—CO— or —N—SO2—;
- at least one hydrogen atom of any of the alkyl group, the alkoxy group, the acyl group, the alkoxycarbonyl group, the acyloxy group, the alkylsulfonyl group, and the arylsulfonyl group can be substituted by a halogen atom, a hydroxy group, an unsubstituted amino group, or a substituted amino group;
- —O— or —NR20— can be inserted between carbon atoms of any of the alkyl group and the alkoxy group;
- R20 represents a hydrogen atom or a C1-C20 alkyl group;
- R2 through R4 are substituents which are not hydrogen atoms and each independently represent a C1-C4 alkyl group, a C1-C4 alkoxy group, a halogen atom, or a cyano group;
- at least one hydrogen atom of any of the alkyl group and the alkoxy group can be substituted by a halogen atom or a hydroxy group;
- n, p, and q are each independently an integer of 0 to 2;
- R5a is (i) a C1-C10 alkyl group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms;
- and
- R5b is (i) a C1-C10 alkyl group in which a hydrogen atom is substituted by at least one hydroxy group or (ii) a C1-C10 alkyl group which has carbon atoms and in which at least one —O— is inserted between the carbon atoms.
Dependencies are inferred from the claim text.