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US 2018/0022894 A1Published application
Polyethylene compositions with improved optical properties
AssigneeDow Global Technologies LLC
InventorsMartin K. Hill, Selim Bensason, Hans-Werner Schmidt, Paul Smith, Seda Aksel
Life of this patent
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Abstract
Embodiments of a polyethylene composition comprise at least 50% by wt. of at least one polyethylene polymer; and 0.001 to 2% by wt. of bisamide nucleating agent utilized to reduce haze within the polyethylene composition.
Claims17
A polyethylene composition comprising:
- at least 50% by wt. of at least one polyethylene polymer chosen from a linear low density polyethylene polymer (LLDPE), a low density polyethylene polymer (LDPE), a high density polyethylene polymer (HDPE), or combinations thereof;
- and
- 0.001 to 2% by wt nucleating agent comprising a structure of formulas (I), (II), or (III):
- wherein R1 and R2 comprise the same or different moieties chosen from:
- C1-C20 alkyl unsubstituted or substituted by one or more hydroxy;
- C4-C20 alkenyl unsubstituted or substituted by one or more hydroxy;
- C2-C20 alkyl interrupted by oxygen or sulfur;
- C3-C12 cycloalkyl unsubstituted or substituted by one or more C1-C20 alkyl;
- (C3-C12 cycloalkyl)-C1-C10 alkyl unsubstituted or substituted by one or more C1-C20 alkyl;
- bis[C3-C12 cycloalkyl]-C1-C10 alkyl unsubstituted or substituted by one or more C1-C20 alkyl;
- a bicyclic or tricyclic hydrocarbon radical with 5 to 20 carbon atoms unsubstituted or substituted by one or more C1-C20 alkyl;
- phenyl unsubstituted or substituted by one or more radicals selected from C1-C20 alkyl, C1-C20 alkoxy, C1-C20 alkylamino, di(C1-C20 alkyl)amino, hydroxy and nitro;
- phenyl-C1-C20 alkyl unsubstituted or substituted by one or more radicals selected from C1-C20 alkyl, C3-C12 cycloalkyl, phenyl, C1-C20 alkoxy and hydroxy;
- phenylethenyl unsubstituted or substituted by one or more C1-C20 alkyl;
- biphenyl-(C1-C10 alkyl) unsubstituted or substituted by one or more C1-C20 alkyl;
- naphthyl unsubstituted or substituted by one or more C1-C20 alkyl;
- naphthyl-C1-C20 alkyl unsubstituted or substituted by one or more C1-C20 alkyl;
- naphthoxymethyl unsubstituted or substituted by one or more C1-C2 alkyl;
- biphenylenyl, flourenyl, anthryl;
- a 5-to-6-membered heterocylic radical unsubstituted or substituted by one or more C1-C20 alkyl;
- a C1-C20 hydrocarbon radical containing one or more halogen;
- or tri(C1-C10 alkyl)silyl(C1-C10 alkyl);
- wherein, when the polyethylene composition is used to form an article, the article has a haze value reduction of at least 15% when compared to an article having the same polyethylene polymer but free of the nucleating agent.
20 more elements
(canceled)
An article produced from the polyethylene composition of any of the preceding claims, wherein the article has a haze value reduction of at least 20% when compared to an article having the same polyethylene polymer but free of the nucleating agent.
(canceled)
Dependencies are inferred from the claim text.