Methods of making halogenated partially fluorinated compounds

A compound having the following structure:

• Br—CF2—CFH—CF2—I, CF3—O—CFH—CF2—I, C3F7—O—CFH—CF2—Z, CF3—CF2—CF2—O—CF(CF3)—CF2—O—CFH—CF2—Z, I—(CF2)n—CFH—CF2—I, I—(CF2)m—CFH—CF2—Br, Br—(CF2)m—CFH—CF2—I, Br—(CF2)q—CFH—CF2—Br, CF3—O—(CF2)3—O—CFH—CF2—Z, Z—CF2—CFH—O—(CF2)n—O—CF═CF2, Z—CF2—CFH—O—(CF2)n—O—CFH—CF2—Z, Z—CF2—CFH—O—(CF2)n—O—CF2—CF═CF2, Z—CF2—CFH—O—(CF2)n—O—CF2—CFH—CF2—Z, CF2═CF—O—(CF2)n—O—CF2—CFH—CF2—Z, Z—CF2—CFH—CF213 O—(CF2)n—O—CF2—CF═CF2, Z—CF2—CFH—CF2—O—(CF2)n—O—CF2—CFH—CF2—Z, X′—CF2—CF2—O—(CF2)n—O—CF2CFH—CF2—Z, X′—CF2—CF2—O—CFH—CF2—Z, X′—CF2—CF2—O—CF2—CFH—CF2—Z, X′—CF(CF3)—CF2—O—CFH—CF2—Z, X′—CF(CF3)—CF2—O—CF2—CFH—CF2—Z, X′—CF2—CF2—(O—CF(CF3)—CF2)p—O—CFH—CF2—Z, X′—CF2—CF2(O—CF(CF3)—CF2)p—O—CF2—CFH—CF2—Z, X′—CF2—CF2—CF2—O—CFH—CF2—Z, X′—CF2—CF2—CF2—O—CF2—CFH—CF2—Z, X′—CF2—CF2—CF2—(O—CF(CF3)—CF2)p—O—CFH—CF2—Z, X′—CF2—CF2—CF2—(O—CF(CF3)—CF2)p—O—CF2—CFH—CF2—Z, X′—CF2—CF2—O—(CF2)2—(O—CF(CF3)CF2)p—O—CFH—CF2—Z, wherein Z is Br, I;
• X′ is selected from Br, I, C(O)X″, and SO2X″ wherein X″ is selected from F, Cl, OH, and salts thereof;
• m is an integer from 1-4;
• n is an integer from 2-4;
• and p is 1 or 2;
• and q is 3 or 4.