Process for production of magnesium fluoride sol solutions from alkoxides comprising addition of magnesium salts
AssigneeNanofluor GmbH
InventorErhard KEMNITZ
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AssigneeNanofluor GmbH
InventorErhard KEMNITZ
Estimating the term…
The invention relates to a method for obtaining a magnesium fluoride (MgF2) sol solution, comprising the steps of providing a magnesium alkoxide precursor in a non-aqueous solvent and adding 1.85 to 2.05 molar equivalents of non-aqueous hydrofluoric acid, characterized in that the reaction proceeds in the presence of a second magnesium fluoride precursor selected from the group of salts of strong, volatile acids, such as a chloride, bromide, iodide, nitrate or triflate of magnesium, or of a catalytic amount of a strong, volatile acid; and/or an additive non-magnesium fluoride precursor selected from the group of salts of strong, volatile acids, such as a chloride, bromide, iodide, nitrate or triflate of lithium, antimony, tin calcium, strontium, barium, aluminium, silicium, zirconium, titanium or zinc. The invention further relates to sol solutions, method of applying the sol solutions of the invention to surfaces as a coating, and to antireflective coatings obtained thereby.
A magnesium fluoride sol solution comprising:
A surface coating obtained by a method comprising
A surface coating comprising sintered magnesium fluoride nanoparticles having a diameter size of lower than 20 nm, a refractive index of between n500=1.19 and n500=1.32, and a porosity between 25% and 40%, and wherein the surface coating has a scratch resistance according DIN EN 13523-4 (pencil test).
Dependencies are inferred from the claim text.