A positive electrode active material for a lithium ion secondary battery, the material comprising:
- a first active material selected from active materials represented by composition formula (1);
- and
- a second active material represented by composition formula (2), wherein
- a ratio a/b of an average particle diameter a of the first active material to an average particle diameter b of the second active material is in a range of 1≦a/b≦60, wherein
- LiwNix(M1)y(M2)zO2 (1)
- where M1 is at least one element selected from Co and Mn, M2 is at least one element selected from Al, Fe, Cr, Ba, Mn, and Mg, 0.9<w<1.1, 2.0<(x+y+z+w)≦2.1, 0.3<x<0.95, 0.01<y<0.4, and 0.001<z<0.2, and
- LiaVOPO4 (2)
- where 0<α≦1.2.