Automatic dishwashing detergent
AssigneesRohm and Haas Company, Union Carbide Chemicals & Plastics Technology Corporation
InventorsRobert Krasnansky, Severine Ferrieux, Bertrand Ammeux, Jan Edward Shulman, Eric P. Wasserman
Life of this patent
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Abstract
A dishwashing detergent comprising a builder; a surfactant; a first polymer comprising monoethylenically unsaturated C3-C6 carboxylic acid units and C1-C12 alkyl (meth)acrylate units; and a dispersant comprising a second polymer comprising monoethylenically unsaturated C3-C6 carboxylic acid units.
Claims17
A phosphate-free dishwashing composition, comprising:
- 5 to 99 wt % of a builder;
- 0.1 to 15 wt % of a surfactant of Formula 1, Formula 2, or a combination thereof,
- R1O—(CH2CH2O)m—(CH2CHR2O)n—R3 (1),
- R3O—(CH2CHR2O)n/2—(CH2CH2O)m/2—R5O—(CH2CH2O)m/2—(CH2CHR2O)n/2—R3 (2),
- wherein R1 is a C8-C24 alkyl group, R2 is a C1-C5 alkyl group, R3 is hydrogen, a C1-C12 alkyl group, a C1-C12 arylalkyl group, or a group represented by the Formula 3,
- —CH2CH(OH)CH2-E-R4, (3)
- wherein E is a C1-C8 alkylene group or an oxygen atom, and R4 is a C1-C8 alkyl group,
- m is a number between 1 and 100, and n is a number between 0 and 50, and R5 is a C1-C8 alkylene group;
- 0.05 and 5 wt % of a first polymer having a weight-average molecular weight between 35,000 and 100,000 g/mol and comprising
- 22 to 80 wt % of monoethylenically unsaturated C3-C6 carboxylic acid units, and
- 20 to 78 wt % of C1-C12 alkyl (meth)acrylate units;
- and
- 0.5 to 10 wt % of a dispersant comprising a second polymer having a weight-average molecular weight between 1,000 and 30,000 g/mol and comprising 50 to 100 wt % of monoethylenically unsaturated C3-C6 carboxylic acid units;
- wherein the phosphate-free dishwashing composition comprises less than 0.5 wt % of a phosphate-containing compound, based on a total weight of the dishwashing composition.
A phosphate-free dishwashing composition, comprising:
- 5 to 99 wt % of a builder;
- 1 to 8 wt % of a surfactant of Formula 1,
- R1O—(CH2CH2O)m—(CH2CHR2O)n—R3 (1),
- wherein R1 is a C8-C24 alkyl group, R2 is a C1-C5 alkyl group, R3 is hydrogen, m is a number between 10 and 30, and n is a number between 0 and 8;
- 0.05 and 1 wt % of a first polymer having a weight-average molecular weight between 35,000 and 100,000 g/mol and comprising
- 22 to 80 wt % of monoethylenically unsaturated C3-C6 carboxylic acid units, and
- 20 to 78 wt % of C1-C12 alkyl acrylate units;
- and
- 1 to 8 wt % of a dispersant comprising a second polymer having a weight-average molecular weight between 1,000 and 30,000 g/mol and comprising 50 to 100 wt % of monoethylenically unsaturated C3-C6 carboxylic acid units;
- wherein the phosphate-free dishwashing composition comprises less than 0.5 wt % of a phosphate-containing compound, based on a total weight of the dishwashing composition.
A method of manufacturing a dishwashing composition, the method comprising contacting
- 5 to 99 wt % of a builder;
- 0.1 to 15 wt % of a surfactant of Formula 1, Formula 2, or a combination thereof,
- R1O—(CH2CH2O)m—(CH2CHR2O)n—R3 (1),
- R3O—(CH2CHR2O)n/2—(CH2CH2O)m/2—R5O—(CH2CH2O)m/2—(CH2CHR2O)n/2—R3 (2),
- wherein R1 is a C8-C24 alkyl group, R2 is a C1-C5 alkyl group, R3 is hydrogen or a C1-C12 alkyl or arylalkyl group or a group represented by the Formula 3,
- —CH2CH(OH)CH2-E-R4, (3),
- wherein E is a C1-C8 alkylene group or an oxygen atom, and R4 is a C1-C8 alkyl group,
- m is a number between 1 and 100, and n is a number between 0 and 50, and R5 is a C1-C8 alkylene group;
- 0.05 and 5 wt % of a first polymer having a weight-average molecular weight between 35,000 and 100,000 g/mol and comprising
- 22 to 80 wt % of monoethylenically unsaturated C3-C6 carboxylic acid units, and
- 20 to 78 wt % of C1-C12 alkyl (meth)acrylate units;
- and
- 0.5 to 10 wt % of a dispersant comprising a second polymer having a weight-average molecular weight between 1,000 and 30,000 g/mol and comprising 50 to 100 wt % of monoethylenically unsaturated C3-C6 carboxylic acid units;
- wherein the dishwashing composition comprises less than 0.5 wt % of a phosphate-containing compound, based on a total weight of the dishwashing composition.
Dependencies are inferred from the claim text.