Source of phosphate for agriculture and the food industry
AssigneeEcophos S.A.
InventorMOHAMED TAKHIM
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Abstract
A source of phosphate for agriculture and food industry comprises a phosphate salt in solid form of formula Mn(HPO4)y.zH2O in which M is Na, K, NH4, n=2, and y=1; or M is Ca, n=1, y=1; or M is Al or Fe, n=2, y=3; and in which z is 0, 1 or 2, wherein said phosphate salt has a phosphate content expressed as a P2O5 content of between 30 and 50% by weight of the phosphate salt, and it has a cadmium content lower than 0.40 ppm.
Claims22
1-50. (canceled)
A phosphate salt in solid form of formula Mn(HPO4)y.zH2O in which M is Na, K, NH4, n=2, and y=1;
- or M is Ca, n=1, y=1;
- or M is Al or Fe, n=2, y=3;
- and in which z is 0, 1 or 2;
- said phosphate salt has a phosphate content expressed as a P205 content of between 30 and 50% by weight of the phosphate salt, wherein the cadmium content in said phosphate salt is less than 0.40 ppm.
A method for the preparation of the phosphate salt according to claim 1, the method comprising the following steps:
- a) a phosphate source digestion using a first aqueous solution of hydrochloric acid, with formation of an attack liquor consisting of an aqueous phase comprising phosphate ions and chloride ions in solution, and a first insoluble solid phase containing impurities,
- b) a first separation between the aqueous phase comprising phosphate and chloride ions in solution and the first insoluble solid phase containing impurities,
- c) a neutralisation of said aqueous phase comprising phosphate ions and chloride ions in solution at a pH sufficient to form an aqueous medium comprising chloride ions and to precipitate the phosphate ions in the form of said phosphate salt,
- d) a second separation between said aqueous medium comprising chloride ions and said phosphate salt,
- wherein steps a) and b) are performed at a temperature between 50° C. and 70° C. for a duration less than two hours and in that said first aqueous solution of hydrochloric acid has an HCl concentration less than or equal to 15% by weight.
Dependencies are inferred from the claim text.