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US 2016/0284947 A1Published application
Novel color converter
AssigneeBASF SE
InventorsMartin KOENEMANN, Gerhard WAGENBLAST, Robert SEND, Sorin IVANOVICI, Gerardus DEKEYZER
Life of this patent
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Abstract
Color converter comprising at least one polymer and at least one organic fluorescent dye comprising at least one structural unit of the formula (I) where the structural unit may be mono- or polysubstituted by identical or different substituents and where one or more CH groups of the six-membered ring of the benzimidazole structure shown may be replaced by nitrogen.
Claims3
1-23. (canceled)
24:
- A polymer mixture, comprising at least one polymer and at least one organic fluorescent dye, comprising at least one structural unit of the formula (II)
- wherein:
- one or more CH groups of the six-membered ring of the benzimidazole structure of the structural unit are optionally replaced by nitrogen and the symbols are each defined as follows:
- n is a number from 1, 2, 3, 4 or to 5 for each structural unit of the formula (II);
- (X—R) is phenyl, tolyl, ethylphenyl, ortho/meta/para xylyl, mesityl, naphthyl, anthranyl, phenanthrenyl, pyrenyl, benzopyrenyl, fluorenyl, indanyl, indenyl, tetralinyl, phenoxy, thiophenoxy, 4-ethoxyphenyl, each of which may be mono- or polysubstituted by identical or different radicals (i), (ii), (iii), (iv) and/or (v):
- (i) C1-C30-alkyl whose carbon chain may comprise one or more —O—, —S—, —NR1—, —C≡C—, —CR1=CR1- and/or —CO— moieties and which may be mono- or polysubstituted by:
- C1-C12-alkoxy, hydroxyl, halogen, cyano and/or aryl which may be mono- or polysubstituted by C1-C18-alkyl and/or C1-C6-alkoxy;
- (ii) C3-C8-cycloalkyl whose carbon skeleton may comprise one or more —O—, —S—, —NR1—, —CR1=CR1- and/or —CO— moieties and which may be mono- or polysubstituted by C1-C18-alkyl, C1-C12-alkoxy and/or C1-C6-alkylthio;
- (iii) aryl or hetaryl, to each of which may be fused further 5- to 7-membered saturated or unsaturated rings whose carbon skeleton may comprise one or more —O—, —S—, —NR1—, —N═CR1—, —CR1=CR1—, —CO—, —SO— and/or —SO2— moieties, where the overall ring system may be mono- or polysubstituted by:
- C1-C18-alkyl, C1-C12-alkoxy, —C═CR1—, —CR1=CR1—, hydroxyl, halogen, cyano, —NR2R3, —NR2COR3, —CONR2R3, —SO2NR2R3, —COOR2 and/or —SO3R2;
- (iv) a —U-aryl radical which may be mono- or polysubstituted by the above radicals mentioned as substituents for the aryl radicals (iii), where U is a —O—, —S—, —NR1—, —CO—, —SO— or —SO2— moiety;
- (v) C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR1, —CR1=CR12, hydroxyl, mercapto, halogen, cyano, nitro, —NR2R3, —NR2COR3, —CONR2R3, —SO2NR2R3, —COOR2 or —SO3R2;
- R1, R2, R3 are each independently hydrogen;
- C1-C18-alkyl whose carbon chain may comprise one or more —O—, —S—, —CO—, —SO— and/or —SO2— moieties and which may be mono- or polysubstituted by C1-C12-alkoxy, C1-C6-alkylthio, hydroxyl, mercapto, halogen, cyano, nitro and/or —COOR1;
- aryl or hetaryl, to each of which may be fused further saturated or unsaturated 5- to 7-membered rings whose carbon skeleton may comprise one or more —O—, —S—, —CO— and/or —SO2— moieties, where the overall ring system may be mono- or polysubstituted by C1-C12-alkyl and/or the above radicals mentioned as substituents for alkyl.
12 more elements
25:
- A fluorescent dye, dye selected from the group consisting of:
- and mixtures thereof,
- wherein:
- n is a number from 0 to (10-p) for each structural unit of the formula (II);
- p is the number of CH units which have been replaced by nitrogen in the six-membered ring of the benzimidazole structure;
- and
- R1 independently represents hydrogen, C1-C18-alkyl or cycloalkyl, the carbon chain of which may comprise one or more —O—, —S—, —CO—, —SO— and/or —SO2— moieties and which may be mono- or polysubstituted;
- aryl or hetaryl which may be mono- or polysubstituted.
5 more elements