Unit and process for purification of crude methyl methacrylate
AssigneeArkema France
InventorsYves BERNARDIN, Romain BILLON, Xavier MARCARIAN, Florent WALLET
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AssigneeArkema France
InventorsYves BERNARDIN, Romain BILLON, Xavier MARCARIAN, Florent WALLET
Estimating the term…
The invention relates to a purification unit (200) which is able to separate crude MMA from light and heavy impurities in order to obtain high quality of MMA, suitable to produce optimal grade polymethylmethacrylate (PMMA). The unit (200) comprises two distillation columns (210, 250) in series, fed with mixture to be distilled in their median part, in order to separate each column in two upper (213, 253) and lower (212, 252) parts, the first distillation column (210) being fed with crude prewashed MMA, and the second distillation column (250) being fed with distilled liquid stream containing MMA, separated from light impurities, issued from bottom of first distillation column (210). The upper part (213) of first distillation column (210) is connected to a lateral extraction system (220), able to minimize MMA content in light impurities flowing upward said first column (210).
A methyl methacrylate purification unit (200) able to separate methyl methacrylate (MMA) from light and heavy impurities, said unit being characterized in that it comprises two distillation columns (210, 250) in series, fed with the mixture to be distilled in their median part, in order to separate each column in two upper (213, 253) and lower (212, 252) parts, the first distillation column (210) being fed with crude prewashed methyl methacrylate (MMA), and the second distillation column (250) being fed with distilled liquid stream containing methyl methacrylate (MMA), separated from light impurities, issued from the bottom of first distillation column (210), and the upper part (213) of the first distillation column (210) is connected to a lateral extraction system (220), able to minimize methyl methacrylate (MMA) content in a gas phase of light impurities flowing upward said first column (210).
Process fir purifying crude methyl methacrylate (MMA), said crude methyl methacrylate (MMA) being prewashed with water before the purification said process comprises the following steps:
Process according to dam 20, wherein said pressure is controlled so as to prevent polymerization of MMA and differential pressure between the top and the bottom of each column is supervised so as to prevent flooding, dogging and fouling of said columns.
Process according to slim 20, wherein the distilled liquid phase comprising heavy impurities exiting the bottom of second distillation column (250) is pumped towards an esterification unit of a MMA production plant.
Dependencies are inferred from the claim text.