Metal-organic frameworks with a high density of highly charged exposed metal cation sites
AssigneeThe Regents of the University of California
InventorsJeffrey R. Long, Matthew T. Kapelewski, Stephen J. Geier
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Abstract
The disclosure provides for Metal-Organic Frameworks comprising M2(m-dobdc)-based cores, and methods of use thereof, including gas separation, gas storage, sensing, and other applications utilizing a high density of exposed metal cation sites.
Claims29
A porous metal-organic framework (MOF) comprising a plurality of cores, wherein the plurality of cores comprise two or more metals, metal ions, and/or metal containing complexes that are linked together by forming covalent bonds with oxide and/or carboxylate linking clusters of 4,6-dioxido-1,3-benzenedicarboxylate (“m-dobdc”) based linking moieties.
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Dependencies are inferred from the claim text.