Use of tetrahydrobenzoxazines as stabilisers
AssigneeBASF SE
InventorsArno LANGE, Helmut MACH, Hans Peter RATH, Dietmar POSSELT
Life of this patent
Estimating the term…
Abstract
The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.
Claims16
1-10. (canceled)
An antioxidant for stabilizing mineral oil products and fuels against the action of light, oxygen and heat, comprising:
- a tetrahydrobenzoxazine of formula I:
- wherein R1 is a hydrocarbyl radical having from 1 to 3000 carbon atoms which is interrupted by at least one selected from the group consisting of O, S and NR6 moieties,
- R6 is a hydrogen atom or a C1- to C4-alkyl radical, and
- R2, R3, R4 and R5 are each independently a hydrogen atom, a hydroxyl group or a hydrocarbyl radical having from 1 to 3000 carbon atoms which may optionally be interrupted by one or more selected from the group consisting of O, S and NR6 moieties,
- wherein R4 may optionally be a radical of formula Y
- wherein R1, R2, R3 and R5 are each as defined above and X is a hydrocarbon bridging element which consists of one or more isobutene units or comprises one or more isobutene units, or wherein R4 may optionally be a radical of the formula Z or Z′
- wherein R1, R2, R3 and R5 are each as defined above and R10 and R11 are each independently hydrogen or a C1- to C10-alkyl radical,
- and wherein R2 and R3 or R3 and R4 or R4 and R5, together with the part-structure —O—CH2—NR7—CH2— attached to the benzene ring, may optionally form a second tetrahydrooxazine ring, or R2 and R3 and R4 and R5, together with the part-structures —O—CH2—NR7—CH2— and —O—CH2—NR8—CH2— attached to the benzene ring, may optionally form a second and a third tetrahydrooxazine ring,
- wherein R7 and R8 are each independently a hydrocarbyl radical having from 1 to 3000 carbon atoms and are interrupted by one or more heteroatoms selected from the group consisting of O, S and NR6 moieties, with the proviso that at least one of R2, R3, R4, or R5 is a polyisobutenyl radical having a number-average molecular weight Mn of from 200 to 40,000.
Dependencies are inferred from the claim text.