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US 2015/0232398 A1Published application
Azulene and derivatives thereof as colorants
OwnerHeinz Langhals, Moritz Eberspächerinventors
Life of this patent
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Abstract
Disclosed is the use of azulene or azulene derivatives for coloring compounds selected from siloxanes and perfluorinated compounds, and compositions that contain azulene or an azulene derivative together with a siloxane or a perfluorinated compound.
Claims16
Use of azulene or an azulene derivative of the general formula (II):
- for coloring a compound selected from a siloxane, a perfluorocarbon compound, a perfluoroether and a perfluoro amine,
- wherein in formula (II) the groups R1 to R8 can be the same or different and are independently selected from a hydrogen atom, a halogen atom, a cyano group, a linear alkyl group, a group —(CH2)n-phenyl, a group —(CH2)n-pyridyl, a group —(CH2)n-thiophene, wherein n is an integer from 0 to 6, a naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or an anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms,
- wherein the linear alkyl group is an alkyl group with at least one and at most 37 C-atoms, wherein one to 10 CH2 units can independently be replaced each with a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a cis- or trans-CH═CH group, wherein one CH unit can also be replaced with a nitrogen atom, an acetylenic C≡C group, a divalent phenyl group (e.g. a 1,2-, 1,3- or 1,4-phenyl group), a divalent pyridine group, a divalent thiophene group, a divalent naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or a divalent anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms,
- wherein up to 12 individual hydrogen atoms of the CH2 groups in an alkyl group can independently be replaced even on the same C-atom each with a halogen atom, a cyano group, or a linear alkyl chain with up to 18 C-atoms, wherein one to 6 CH2 units can independently be replaced with a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a cis- or trans-CH═CH group, wherein one CH unit can also be replaced with a nitrogen atom, an acetylenic C≡C group, a divalent phenyl group, a divalent pyridine group, a divalent thiophene group, a divalent naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or a divalent anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms, and wherein up to 12 individual hydrogen atoms of the CH2 groups in the alkyl chain which can serve as the substituent at the alkyl group can independently be replaced even on the same C-atom each with a halogen atom, a cyano group, or a linear alkyl chain with up to 18 C-atoms, wherein one to 6 CH2 units can independently be replaced each with a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a cis- or trans-CH═CH group, wherein one CH unit can also be replaced with a nitrogen atom, an acetylenic C≡C group, a divalent phenyl group, a divalent pyridine group, a divalent thiophene group, a divalent naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or a divalent anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms,
- and wherein two linear alkyl groups as defined above and located at different positions R1 to R8 can optionally be linked to each other forming a ring.
2 more elements
Composition comprising a compound selected from siloxane, a perfluorocarbon compound, a perfluoroether, a perfluoroamine and mixtures thereof as a main component, based on the total weight of the composition, and azulene or an azulene derivative of the formula (II),
- wherein in formula (II) the groups R1 to R8 can be the same or different and are independently selected from a hydrogen atom, a halogen atom, a cyano group, a linear alkyl group, a group —(CH2)n-phenyl, a group —(CH2)n-pyridyl, a group —(CH2)n-thiophene, wherein n is an integer from 0 to 6, a naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or an anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms,
- wherein the linear alkyl group is an alkyl group with at least one and at most 37 C-atoms, wherein one to 10 CH2 units can independently be replaced each with a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a cis- or trans-CH═CH group, wherein one CH unit can also be replaced with a nitrogen atom, an acetylenic C≡C group, a divalent phenyl group, a divalent pyridine group, a divalent thiophene group, a divalent naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or a divalent anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms,
- wherein up to 12 individual hydrogen atoms of the CH2 groups in an alkyl group can independently be replaced even on the same C-atom each with a halogen atom, a cyano group, or a linear alkyl chain with up to 18 C-atoms, wherein one to 6 CH2 units can independently be replaced each with a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a cis- or trans-CH═CH group, wherein one CH unit can also be replaced with a nitrogen atom, an acetylenic C≡C group, a divalent phenyl group, a divalent pyridine group, a divalent thiophene group, a divalent naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or a divalent anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms, and wherein up to 12 individual hydrogen atoms of the CH2 groups in the alkyl chain which can serve as the substituent at the alkyl group can independently be replaced also on the same carbon atom each with a halogen atom, a cyano group, or a linear alkyl chain with up to 18 C-atoms, wherein one to 6 CH2 units can independently be replaced with a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a cis- or trans-CH═CH group, wherein one CH unit can also be replaced with a nitrogen atom, an acetylenic C≡C group, a divalent phenyl group, a divalent pyridine group, a divalent thiophene group, a divalent naphthalene group, wherein one or two CH groups can be replaced with nitrogen atoms, or a divalent anthracene group, wherein one or two CH groups can be replaced with nitrogen atoms,
- and wherein two linear alkyl groups as defined above and located at different positions R1 to R8 can optionally be linked to each other forming a ring;
- and
- wherein the azulene or azulene derivative of formula (II) is dissolved in the compound selected from a siloxane, a perfluorocarbon compound, a perfluoroether, a perfluoroamine and combinations thereof.
3 more elements
16-17. (canceled)
Dependencies are inferred from the claim text.