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US 2015/0143786 A1Published application
Aluminum titanate compositions, ceramic articles comprising same, and methods of manufacturing same
AssigneeCorning Incorporated
InventorsGregory Albert Merkel, Patrick David Tepesch, Elizabeth Marie Vileno
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Abstract
Disclosed are ceramic bodies comprised of a tialite phase and at least one silicate phase with a rare earth oxide and zirconium additions and methods for the manufacture of the same.
Claims33
A ceramic article, comprising:
- a tialite phase;
- at least one silicate phase;
- at least 1 wt % MgO;
- at least 0.1 wt % rare earth oxide;
- at least 0.1 wt % ZrO2,
- wherein metal oxide constituents of the article satisfy at least one of the relations
- 3(mole % TiO2)/(100+mole % Al2O3)<1.0 and
- [2(mole % Al2O3)+3(mole % MgO)]/110>1.0,
- where mole % TiO2=100[(moles TiO2)/(moles TiO2+moles Al2O3+moles MgO+moles ZrO2)], mole % Al2O3=100[(moles Al2O3)/(moles TiO2+moles Al2O3+moles MgO+moles ZrO2)], and mole % MgO=100[(moles MgO)/(moles TiO2+moles Al2O3+moles MgO+moles ZrO2)],
- wherein the sum of ZrO2 and the rare earth oxide is greater than 0.5 wt %, and
- wherein the amount of Fe2O3 is less than 0.5 wt %.
8 more elements
A method of manufacturing a ceramic article, comprising:
- providing an inorganic batch composition comprising a silicon containing source, an aluminum containing source, a titanium containing source, a magnesium containing source, a rare earth containing source and a zirconium containing source;
- mixing the inorganic batch composition together with one or more processing aid selected from the group consisting of a plasticizer, lubricant, binder, pore former, and solvent, to form a plasticized ceramic precursor batch composition;
- shaping the plasticized ceramic precursor batch composition into a green body;
- and
- firing the green body under conditions effective to convert the green body into a ceramic article comprising:
- a tialite phase;
- at least one silicate phase;
- at least 1 wt % MgO;
- at least 0.1 wt % rare earth oxide;
- and
- at least 0.1 wt % ZrO2,
- wherein metal oxide constituents of the article satisfy at least one of the relations
- 3(mole % TiO2)/(100+mole % Al2O3)<1.0 and
- [2(mole % Al2O3)+3(mole % MgO)]/110>1.0,
- where mole % TiO2=100[(moles TiO2)/(moles TiO2+moles Al2O3+moles MgO+moles ZrO2)], mole % Al2O3=100[(moles Al2O3)/(moles TiO2+moles Al2O3+moles MgO+moles ZrO2)], and mole % MgO=100[(moles MgO)/(moles TiO2+moles Al2O3+moles MgO+moles ZrO2)],
- wherein the sum of ZrO2 and the rare earth oxide is greater than 0.5 wt %, and
- wherein the amount of Fe2O3 is less than 0.5 wt %.
14 more elements
Dependencies are inferred from the claim text.