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US 2014/0235894 A1Published application
Method for producing alpha,beta-unsaturated carboxylic acid-n,n-disubstituted amide and method for producing 3-alkoxycarboxylic acid-n,n-disubstituted amide
AssigneeIdemitsu Kosan Co., Ltd.
InventorsHinonori TASHIRO, Yasushi SHIRAKI, Makoto KASHIMA
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Abstract
The invention is directed to a technique for effectively producing an amide compound suitable for use as a solvent or a detergent on a large scale and at low cost.
Claims15
A method for producing an N,N-disubstituted-β-amino acid, comprising:
- reacting an α,β-unsaturated carboxylic acid with a secondary amine,
- wherein a ratio by mole of the secondary amine to the α,β-unsaturated carboxylic acid, secondary amine/α,β-unsaturated carboxylic acid), is 3 to 10, and
- wherein the reacting is carried out at 10 to 60° C.
A method for producing an α,β-unsaturated carboxylic acid-N,N-disubstituted amide, the method comprising:
- adding a vapor-phase-polymerization inhibitor to an N,N-disubstituted-β-amino acid-N′,N′-disubstituted amide in liquid form;
- decomposing the N,N-disubstituted-β-amino acid-N′,N′-disubstituted amide at 200 to 300° C. and at a pressure of 0.15 to 0.95 MPa, to thereby produce an α,β-unsaturated carboxylic acid-N,N-disubstituted amide in vapor form;
- and
- adding a liquid-phase-polymerization inhibitor to the α,β-unsaturated carboxylic acid-N,N-disubstituted amide.
1 more element
A method for producing an α,β-unsaturated carboxylic acid-N,N-disubstituted amide, the method comprising:
- (I) adding an α,β-unsaturated carboxylic acid to a secondary amine, to obtain a resultant mixture, and allowing reaction of the resultant mixture to proceed under pressurized conditions, to obtain a first product;
- (II) reacting the first product with a secondary amine by a countercurrent contact system, to obtain a second product;
- and
- (III) decomposing the second product in the presence of a polymerization inhibitor added thereto.
1 more element
Dependencies are inferred from the claim text.