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US 2014/0234624 A1Published application
Microporous coordination complex and method of making the same
AssigneeThe Regents of the University of Michigan
InventorsAdam J. Matzger, Kyoungmoo Koh
Life of this patent
Estimating the term…
Abstract
Disclosed herein is a three-dimensional coordination complex that includes a plurality of inorganic centers; a plurality of a first bis(bidentate) linker; and a plurality of a second bis(bidentate) linker, where the first and the second bis(bidentate) linkers are have different lengths, and the bidentate binding sites on each linker face in opposite directions on an axis.
Claims48
A three-dimensional coordination complex comprising:
- a plurality of inorganic centers;
- a plurality of a first bis(bidentate) linker having a first length and two bidentate binding sites facing in opposite directions along an axis optionally offset in a transverse direction relative to the axis;
- and,
- a plurality of a second bis(bidentate) linker having a second length and the two bidentate binding sites facing in opposite directions along an axis optionally offset in a transverse direction relative to the axis,
- wherein the longer of the first and second lengths is about 1.1 to about 1.5 times longer than the shorter of the first and second lengths.
2 more elements
A crystalline, porous, homogeneous composition comprising:
- a plurality of Zn4O clusters;
- a plurality of benzene-1,4-dicarboxylate each individually bound to the plurality of Zn4O clusters;
- and,
- a plurality of naphthalene-2,6-dicarboxylate each individually bound to the plurality of Zn4O clusters.
1 more element
A crystalline, porous, homogeneous composition comprising:
- a plurality of Zn4O clusters;
- a plurality of naphthalene-2,6-dicarboxylate each individually bound to the plurality of Zn4O clusters;
- and, a plurality of biphenyl-4,4′-dicarboxylate each individually bound to the plurality of Zn4O clusters.
A method comprising:
- (a) preparing an admixture that comprises
- a precursor complex, and
- a salt, acid, or ester of each of first and second bis(bidentate) linkers, wherein each of the first and second bis(bidentate) linkers has a length and two bidentate binding sites facing in opposite directions along an axis optionally offset in a transverse direction relative to the axis, and wherein the length of the longer of the first and second bis(bidentate) linkers is about 1.1 to about 1.5 times longer than the length of the shorter of the first and second bis(bidentate) linkers;
- and
- (b) precipitating a three-dimensional coordination complex from the admixture.
2 more elements
Dependencies are inferred from the claim text.