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US 2014/0151677 A1Published application
Aromatic amine derivative, and organic electroluminescent element containing same
AssigneeIdemitsu Kosan Co., Ltd.
InventorsTakushi Shiomi, Masami Watanabe, Mitsuru Eida
Life of this patent
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Abstract
An aromatic amine derivative represented by the following formula (1): wherein Z1 is a group represented by the following formula (2); Z2 is a group represented by the following formula (3) or (3′); and P and Q are independently a group represented by the following formula (4) or (5):
Claims11
An aromatic amine derivative represented by the following formula (1):
- [Z1nL1 (1)
- wherein Z1 is a group represented by the following formula (2);
- L1 is a linkage group, and may include one or more substituents;
- and
- n is an integer of 2 to 10:
- [Z2mL2 (2)
- wherein Z2 is a group represented by the following formula (3) or (3′);
- L2 is a linkage group, and may include one or more substituents;
- L1 in the formula (1) bonds to any of Z2 and L2;
- and
- m is an integer of 2 to 10:
- wherein in the formulas (3) and (3′),
- A is a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group including 6 to 25 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group including 5 to 25 ring atoms or a group formed of plural rings;
- A′ is a single bond, a substituted or unsubstituted aromatic hydrocarbon group including 6 to 25 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group including 5 to 25 ring atoms or a group formed of plural rings;
- B is a single bond, a substituted or unsubstituted aromatic hydrocarbon group including 6 to 25 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group including 5 to 25 ring atoms or a group formed of plural rings;
- C is a single bond, a substituted or unsubstituted aromatic hydrocarbon group including 6 to 25 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group including 5 to 25 ring atoms or a group formed of plural rings;
- P and Q are independently a substituted or unsubstituted aromatic hydrocarbon group including 6 to 25 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group including 5 to 25 ring atoms, a group formed of plural rings or a group represented by the following formula (4) or (5);
- L2 in the formula (3) bonds to any of A, B, C, P and Q, and L2 in the formula (3′) bonds to A′;
- and
- k and l are independently an integer of 0 or 1, and k+l≦1:
- wherein in the formula (4), X is —O—, —S—, or —N(Ra)—, Ra is an atom or a group selected from a hydrogen atom, a substituted or unsubstituted linear or branched alkyl group including 1 to 20 carbon atoms, a substituted or unsubstituted linear or branched alkenyl group including 2 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group including 3 to 20 carbon atoms, a trialkylsilyl group of which the alkyl parts are each a substituted or unsubstituted alkyl group including 1 to 20 carbon atoms, a triarylsilyl group of which the aryl parts are each a substituted or unsubstituted aryl group including 6 to 24 ring carbon atoms, an alkylarylsilyl group including a substituted or unsubstituted alkyl group including 1 to 20 carbon atoms and a substituted or unsubstituted aryl group including 6 to 24 ring carbon atoms, a substituted or unsubstituted aryl group including 6 to 25 ring carbon atoms and a substituted or unsubstituted heteroaryl group including 5 to 24 ring atoms;
- R1 and R2 are independently an atom or a group selected from a substituted or unsubstituted linear or branched alkyl group including 1 to 20 carbon atoms, a substituted or unsubstituted linear or branched alkenyl group including 2 to 15 carbon atoms, a substituted or unsubstituted cycloalkyl group including 3 to 20 carbon atoms, a trialkylsilyl group of which the alkyl parts are each a substituted or unsubstituted alkyl group including 1 to 20 carbon atoms, a triarylsilyl group of which the aryl parts are each a substituted or unsubstituted aryl group including 6 to 24 ring carbon atoms, an alkylarylsilyl group including a substituted or unsubstituted alkyl group including 1 to 20 carbon atoms and a substituted or unsubstituted aryl group including 6 to 24 ring carbon atoms, a substituted or unsubstituted aryl group including 6 to 24 ring carbon atoms, a substituted or unsubstituted heteroaryl group including 5 to 24 ring atoms, a halogen atom and a cyano group, and adjacent plural R1s, adjacent plural R2s, and/or adjacent R1 and R2 may bond to each other to form a saturated or unsaturated ring;
- a and b are independently an integer of 0 to 3 and
- Q1 and Q2 are independently a group including 5 to 25 atoms which forms a saturated or unsaturated ring;
- in the formula (5), Ar1 and Ar2 are independently a substituted or unsubstituted aromatic hydrocarbon group including 6 to 25 ring carbon atoms or a substituted or unsubstituted aromatic heterocyclic group including 5 to 25 ring atoms, and at least one of Ar1 and Ar2 is a group formed of plural rings including 9 to 40 ring carbon atoms or a fused aromatic ring group including 10 to 25 ring carbon atoms.
22 more elements
Dependencies are inferred from the claim text.