Polymethacrylimide foams having a reduced residual monomer content, and production method
AssigneeEvonik Roehm GmbH
InventorsKay Bernhard, Mathias Hempler, Stefan Plass, Werner Geyer, Thomas Barthel
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Abstract
The invention relates to a process for producing poly(meth)acrylimide foams and also blocks, sheets and the like composed of such poly(meth)acrylimide foams and also the intermediate articles formed from the copolymer of (meth)acrylic acid and (meth)acrylonitrile, which are all distinguished by a particularly low residual monomer content.
Claims15
A process for producing a poly(meth)acrylimide foam in block or sheet form, the process comprising copolymerizing (meth)acrylic acid and (meth)acrylonitrile with or without further copolymerisable monomers in three process steps of polymerisation;
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- tempering and foaming at three respectively higher process temperatures, wherein a polymerisation mixture contains three initiators, in which decomposition temperatures of the three initiators are such that the first initiator has a one hour half-life below 80° C., the second initiator has a one hour half-life between 80 and 110° C. and the third initiator has a one hour half-life above 110° C., and a product directly after foaming has a (meth)acrylonitrile content below 6000 ppm.
Dependencies are inferred from the claim text.