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US 2012/0083634 A1Published application
Adsorbent Regeneration in Light Olefin Recovery Process
AssigneeUop LLC
InventorJason T. Corradi
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Abstract
A process is presented for the regeneration of adsorbent beds in the light olefin recovery process. The process uses gas generated in the methanol to olefins process to regenerate adsorbent beds. The gas removes the need for external gases, and the gas can be used in the periodic purging of the methanol to olefins reactor.
Claims17
A process for regenerating adsorbents in a methanol to olefin process, comprising:
- passing an oxygenate stream to a methanol to olefins reactor, thereby generating an intermediate olefins stream;
- passing the intermediate olefins stream to an olefins separation unit, wherein the olefins separation unit includes adsorbents for drying and removing contaminants from the olefin streams, and the adsorbents are in fixed beds with the beds not in use in an off-line configuration, and wherein a demethanizer overhead stream is generated;
- passing the demethanizer overhead stream to off-line adsorbents to regenerate the off-line adsorbent beds, thereby creating an adsorbent off-gas;
- and
- passing the adsorbent off-gas to the methanol to olefins reactor as a purge gas.
2 more elements
A process for regenerating adsorbents in a methanol to olefin process, comprising:
- passing an oxygenate stream to a methanol to olefins reactor, thereby generating an intermediate olefins stream;
- compressing the intermediate olefins stream, creating a compressed olefins stream;
- separating the compressed olefins stream into a first stream comprising light olefins and oxygenates, and a second stream comprising C4 and heavier hydrocarbons;
- passing the first stream through an oxygenate adsorber and caustic scrubber, creating a light olefins stream with reduced oxygenate and CO2 content, and a recycle oxygenate stream;
- passing the light olefins stream with reduced CO2 content in a first adsorbent bed, creating a dry light olefins stream with reduced water and CO2 content;
- separating the dry light olefins with reduced CO2 content stream into a third stream comprising C3 and heavier hydrocarbons and a fourth stream comprising C2 and lighter gases;
- separating the fourth stream into a fifth stream comprising ethane and ethylene, and a sixth stream comprising methane and lighter gases;
- during regeneration of the first adsorbent bed, regenerating the adsorbent bed with a portion of the sixth stream, thereby creating a seventh stream;
- and
- passing the seventh stream to the methanol to olefins reactor as a purge gas.
7 more elements
A process for regenerating adsorbents in a methanol to olefin process, comprising:
- passing an oxygenate stream to a methanol to olefins reactor, thereby generating an intermediate olefins stream;
- compressing the intermediate olefins stream, creating a compressed olefins stream;
- separating the compressed olefins stream into a first stream comprising light olefins and oxygenates, and a second stream comprising C4 and heavier hydrocarbons;
- passing the first stream in a first adsorbent bed, creating a light olefins stream with reduced oxygenate and CO2 content, and a recycle oxygenate stream;
- separating the light olefins stream with reduced CO2 content into a third stream comprising C3 and heavier hydrocarbons and a fourth stream comprising C2 and lighter gases;
- separating the fourth stream into a fifth stream comprising ethane and ethylene, and a sixth stream comprising methane and lighter gases;
- passing the third stream to a depropanizing column, thereby creating an overhead stream comprising propane and propylene, and a bottoms stream comprising C4 and heavier hydrocarbons;
- passing the depropanizing overhead stream through a second adsorbent bed, thereby creating a purified C3 stream;
- mixing a portion of the bottoms stream with the sixth stream, and using the mixed stream to regenerate the second adsorbent bed, thereby creating a seventh stream;
- during regeneration of the first adsorbent bed, regenerating the adsorbent bed with a portion of the sixth stream, thereby creating an eighth stream;
- and
- passing the seventh and eighth streams to the methanol to olefins reactor as a purge gas.
9 more elements
Dependencies are inferred from the claim text.