Non-linear opticaly active molecules, their synthesis, and use

A compound represented of one or more of the following general structures:

• where M1=O, S;
• M2=O, S, and M1=, ≠M2.;
• M3=O, CH2;
• M4=O, CH2
• where Z=H, alkane hydrocarbons, fluoroalkane hydrocarbons, fluorinated alkane esters and ethers;
• ZF=fluoroalkane hydrocarbons, fluorinated alkane esters and ethers;
• where D is one or more of the following:
• wherein, M=O, S;
• wherein Z=H, alkane hydrocarbons, fluoroalkane hydrocarbons, fluorinated alkane esters and ethers.
• where R1 is selected from the following
• R1
• (n = 0-11)
• (n = 0-11)
• Partially fluorinated alkanes CnFmH2n+1−m n = 1 to 5, m = 1 to 2n − 1
• CF3—CH2—
• CF3—CH2—CH2—O—CH2—CH2—
• Alkane hydrocarbons CnH2n+1 (n = 1 to 5)
• Partially fluorinated hydrocarbon esters and ethers
• R2
• (n = 0-11)
• (n = 0-11)
• Partially fluorinated alkanes CnFmH2n+1−m (n = 1 to 5, m = 1 to 2n − 1)
• CF3—CH2—
• CF3—CH2—CH2—O—CH2—CH2—
• Partially fluorinated hydrocarbon esters and ethers
• Alkane hydrocarbons CnH2n+1 (n = 1 to 5)
• OH—CH2—CH2—
• R3
• CH3—O—
• CH3—S—
• (n = 1-4)
• Rf = —CH2—CH2—CF3
• (n = 0-11)
• (n = 0-11)
• (n = 1-5, m = 1-5)
• R4
• (n = 1-4)
• Rf = —CH2—CH2—CF3
• (n = 0-11)
• (n = 0-11)
• (n = 1-5, m = 1-5)