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US 2011/0087052 A1Published application
Process for the manufacture of alkenones
AssigneeSolvay SA
InventorsMax Braun, Alain Lambert
Life of this patent
Estimating the term…
Abstract
Process for preparing an alkenone, which comprises (a) reacting a carboxylic acid halide with a vinyl ether by introducing vinyl ether into a liquid reaction medium containing carboxylic acid halide to form a halogenated precursor of the alkenone and (b) eliminating hydrogen halide from said precursor to form the alkenone.
Claims20
A process for preparing an alkenone corresponding to Formula (I):
- R1-C(O)—C(H)═C(H)—OR2 (I) wherein R1 is a fluorinated C1-C4 alkyl group or a CF3C(O)CH2 group, wherein R2 represents aryl, substituted aryl, or a C1-C10 alkyl group which is optionally substituted by at least one halogen atom, which comprises said process comprising:
- (a) reacting a carboxylic acid halide with a vinyl ether by introducing vinyl ether into a liquid reaction medium containing the carboxylic acid halide to form a halogenated precursor of the alkenone;
- and (b) eliminating hydrogen halide from said precursor to form the alkenone,
- wherein said carboxylic acid halide corresponds to Formula (II):
- R1-C(O)X (II) in which X represents fluorine, chlorine, or bromine, and
- wherein said vinyl ether corresponds to Formula (III):
- CH2═C(H)—OR2 (III) in which R2 has the same meaning as for Formula (I).
4 more elements
(canceled)
17-36. (canceled)
Dependencies are inferred from the claim text.