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US 2010/0167050 A1Published application
Bimodal acrylate pressure-sensitive adhesive compounds
AssigneeTesa SE
InventorsMarc Husemann, Stephan Zollner
Life of this patent
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Abstract
The invention relates to a polyacrylate which as a result of a polymerization process has a broad, bimodal molecular weight distribution. These acrylate pressure-sensitive adhesives are preferably processed from the melt. The low molecular weight fraction lowers the flow viscosity, while the high molecular weight fraction results in the achievement of a high shear strength, following appropriate crosslinking, for the acrylate pressure-sensitive adhesive.
Claims6
-8. (canceled)
A pressure-sensitive adhesive comprising a polyacrylate obtained by the process of polymerizing a monomer mixture of
- a1) 70% to 100% by weight acrylic acid and/or acrylic esters of the formula CH2═C(R′)(COOR2), where R′═H or CH3 and R2 is an alkyl chain having 1 to 20 carbon atoms, and
- a2) 0 to 30% by weight olefinically unsaturated monomers containing functional groups,
- in an at least two-phase free-radical solvent polymerization in the presence of an organic solvent or in mixtures of organic solvents to give a polyacrylate having an at least bimodal molecular weight distribution, the polymerization being carried out in a first phase of the at least two-phase polymerization, in the presence of a first initiator concentration, to give a first polymer having a first molecular weight and, before the monomer mixture has been completely consumed by the polymerization, a further phase or phases of polymerization is or are started, by the addition at least once of a regulator, and in this further phase or further phases a second polymer or polymers is or are synthesized, said second polymer having a second molecular weight which second molecular weight is lower than said first molecular weight
- comprising the following monomer units:
- a1) acrylic acid and/or acrylic esters of the formula CH2═C(R′)(COOR2), where R′═H or CH3 and R2 is a linear, branched or cyclic alkyl chain having 1 to 20 carbon atoms,
- at 70%-100% by weight, based on the polymer,
- a2) olefinically unsaturated monomers containing functional groups, at 0-30% by weight, based on the polymer,
- and having a broad, at least bimodal molecular weight distribution, the molecular weight maxima in the molecular weight distributions of at least two polymers being at least 50 000 g/mol apart.
5 more elements
(canceled)
Dependencies are inferred from the claim text.