A method for determining a polyester fraction in a multi-component powder during a thermal spraying process, comprising the steps of heating and feeding the multi-component powder to an object with aid of a carrier, forming a coating on the object, and measuring a first value for an intensity of light emitted by the carrier and measuring a second value for an intensity of light emitted by a combination of the carrier and the multi-component powder, deriving a characteristic value from a comparison using the first and second measured values, and determining a fraction of polyester in the multi-component powder on a basis of a previously determined relationship between the characteristic value and the polyester fraction.