Back to results
US 2010/0144515 A1Published application
Fluorinated dialkoxy-diimino catalyst components
AssigneeTotal Petrochemicals Research Feluy
InventorsJean-Francois Carpentier, Evgueni Kirillov, Thomas Christophe, Abbas Razavi
Life of this patent
Estimating the term…
Abstract
This invention relates to the fluorinated dialkoxy-diimine metal complexes and their use in catalyst system for the polymerisation or oligomerisation of ethylene and alpha-olefins.
Claims11
1-12. (canceled)
A metallic complex formed by a process comprising:
- reacting via a metallation reaction, a metal salt or precursor of formula MX4, wherein M is a metal group 4 of the Periodic Table, and wherein each X is the same or different and is a halogen, an alkyl or a benzyl group with a fluorinated dialcohol-diimine pro-ligand of general formula
- wherein R′ is a bridge having from 1 to 6 carbon atoms, which is optionally substituted so that the substituents form a ring either with each other or with R2;
- each R2 is independently selected from hydrogen, C1 to C20 aryl groups or C1 to C20 alkyl groups optionally substituted with one or more fluorinated groups;
- R3 and R4 are each independently selected from CF3, CnF2n+1, wherein n is an integer between 1 and 10, C1 to C20 aryl groups or C1 to C20 alkyl groups;
- and
- R5 and R6 are each independently selected from hydrogen, C1 to C20 aryl groups or C1 to C20 alkyl groups.
3 more elements
Dependencies are inferred from the claim text.