US 2010/0137134 A1 · Pesticidal Mixtures

Abstract

Pesticidal mixtures comprising, as active components, 1) an anthranilamid compound of the formula I, 2 (I) Y wherein B1 is halogen, alkyl, haloalkyl, or haloalkoxy; B2 is halogen, haloalkyl, alkoxy, haloalkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, alkyl-S(═O)χ-O— or haloalkyl S(O)x-O—, wherein x is 1 or 2 and the alkoxy radical may be substituted; R is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, wherein these groups arc optionally substituted; X is halogen; Y is H or halogen; or the enantiomers or salts or N-oxides thereof, and 2) one or more compounds II selected from group A consisting of organo(thio)-phosphates, carbamates, pyrethroids, growth regulators, nicotinic receptor agonists/antagonists compounds, GABA antagonist compounds, macrocyclic lactone insecticides, METI I acaricides, METI II and III compounds, uncoupler compounds, oxidative phosphorylation inhibitor compounds, mixed function oxidase inhibitor compounds, sodium channel blocker compounds and others, all as defined in the description, in synergistically effective amounts, use of these mixture for combating insects, arachnids or nematodes in and on plants and for the protection of seeds, and for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by parasites.

Claims22

Dependent claims

1-16. (canceled)

A pesticidal mixture comprising,

1) a compound of the formula I
wherein,
B1 is halogen, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-haloalkoxy;
B2 is halogen, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-haloalkoxy-C1-C4-haloalkoxy, C1-C4-alkenyloxy, C1-C4-alkynyloxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkyl-S(═O)x—O— or C1-C4-haloalkyl S(O)x—O—, wherein x is 1 or 2 and the C1-C4-alkoxy radical may be substituted with 1-6 groups selected from halogen, cyano, C1-C4-alkoxy, C1-C4-alkoxycarbonyl;
R is hydrogen, ethyl, n-propyl, butyl, pentyl, hexyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, wherein these groups are unsubstituted or substituted with from 1 to 3 groups selected from halogen, cyano, nitro, C1-C6-alkyloxycarbonyl, amino, C1-C6-alkylamino, di(C1-C6-alkyl)amino, C1-C6-alkoxy, C1-C6-thioalkyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl;
X is halogen;
Y is hydrogen or halogen;
or the enantiomers or salts or N-oxides thereof, and
2) one or more compounds II selected from group A consisting of:
A1:
acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, flupyrazofos, isoxathion, malathion, methamidophos, methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, or trichlorfon;
A2:
alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, or triazamate;
A3:
allethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, or transfluthrin;
A4:
a) benzoylureas, bistrifluron, chlorfluazuron, cyromazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, or clofentezine;
b) halofenozide, methoxyfenozide, tebufenozide, or azadirachtin;
c) pyriproxyfen, methoprene, or fenoxycarb;
or d) spirodiclofen, spiromesifen, or spirotetramat, having the formula Γ1,
A5:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, or thiacloprid;
A6:
acetoprole, endosulfan, ethiprole, fipronil, pyrafluprole, pyriprole, or the phenylpyrazole compound of formula Γ2
A7:
abamectin, emamectin, milbemectin, lepimectin, or spinosad;
A8:
fenazaquin, pyridaben, tebufenpyrad, or tolfenpyrad;
A9:
acequinocyl, fluacypyrim, or hydramethylnon;
A10:
chlorfenapyr;
A11:
cyhexatin, diafenthiuron, fenbutatin oxide, or propargite;
A12:
piperonyl butoxide;
A13:
indoxacarb, or metaflumizone;
and
A14:
amidoflumet, benclothiaz, bifenazate, cartap, cyflumetofen, flonicamid, flufenerim, pyridalyl, pymetrozine, sulfur, thiocyclam or the aminoisothiazole compounds of formula Γ3,
wherein Ri is —CH2OCH2CH3 or H and Rii is CF2CF2CF3 or CH2CH(CH3)3,
wherein said compound of formula I and said one or more compounds II are present in synergistically effective amounts.

41 more elements

A method for protecting plants from attack or infestation by insects, acarids or nematodes comprising,

contacting the plant, or the soil or water in which the plant is growing, with a pesticidally effective amount of a mixture comprising,
1) a compound of the formula I
wherein,
B1 is halogen, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-haloalkoxy;
B2 is halogen, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-haloalkoxy-C1-C4-haloalkoxy, C1-C4-alkenyloxy, C1-C4-alkynyloxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkyl-S(═O)x—O— or C1-C4-haloalkyl S(O)x—O—, wherein x is 1 or 2 and the C1-C4-alkoxy radical may be substituted with 1-6 groups selected from halogen, cyano, C1-C4-alkoxy, C1-C4-alkoxycarbonyl;
R is hydrogen, ethyl, n-propyl, butyl, pentyl, hexyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, wherein these groups are unsubstituted or substituted with from 1 to 3 groups selected from halogen, cyano, nitro, C1-C6-alkyloxycarbonyl, amino, C1-C6-alkylamino, di(C1-C6-alkyl)amino, C1-C6-alkoxy, C1-C6-thioalkyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl;
X is halogen;
Y is hydrogen or halogen;
or the enantiomers or salts or N-oxides thereof, and
2) one or more compounds II selected from group A consisting of:
A1:
acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, flupyrazofos, isoxathion, malathion, methamidophos, methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, or trichlorfon;
A2:
alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, or triazamate;
A3:
allethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, or transfluthrin;
A4:
a) benzoylureas, bistrifluron, chlorfluazuron, cyromazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, or clofentezine;
b) halofenozide, methoxyfenozide, tebufenozide, or azadirachtin;
c) pyriproxyfen, methoprene, or fenoxycarb;
or d) spirodiclofen, spiromesifen, or spirotetramat, having the formula Γ1,
A5:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, or thiacloprid;
A6:
acetoprole, endosulfan, ethiprole, fipronil, pyrafluprole, pyriprole, or the phenylpyrazole compound of formula Γ2
A7:
abamectin, emamectin, milbemectin, lepimectin, or spinosad;
A8:
fenazaquin, pyridaben, tebufenpyrad, or tolfenpyrad;
A9:
acequinocyl, fluacypyrim, or hydramethylnon;
A10:
chlorfenapyr;
A11:
cyhexatin, diafenthiuron, fenbutatin oxide, or propargite;
A12:
piperonyl butoxide;
A13:
indoxacarb, or metaflumizone;
and
A14:
amidoflumet, benclothiaz, bifenazate, cartap, cyflumetofen, flonicamid, flufenerim, pyridalyl, pymetrozine, sulfur, thiocyclam or the aminoisothiazole compounds of formula Γ3,
wherein Ri is —CH2OCH2CH3 or H and Rii is CF2CF2CF3 or CH2CH(CH3)3,
wherein said compound of formula I and said one or more compounds II are present in synergistically effective amounts;
wherein said plants are protected.

43 more elements

A method for controlling insects, arachnids or nematodes comprising,

contacting said insect, arachnid or nematode or their food supply, habitat, breeding grounds or their locus with a pesticidally effective amount of a mixture comprising,
1) a compound of the formula I
wherein,
B1 is halogen, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-haloalkoxy;
B2 is halogen, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-haloalkoxy-C1-C4-haloalkoxy, C1-C4-alkenyloxy, C1-C4-alkynyloxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4haloalkylsulfonyl, C1-C4-alkyl-S(═O)x—O— or C1-C4-haloalkyl S(O)x—O—, wherein x is 1 or 2 and the C1-C4-alkoxy radical may be substituted with 1-6 groups selected from halogen, cyano, C1-C4-alkoxy, C1-C4-alkoxycarbonyl;
R is hydrogen, ethyl, n-propyl, butyl, pentyl, hexyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, wherein these groups are unsubstituted or substituted with from 1 to 3 groups selected from halogen, cyano, nitro, C1-C6-alkyloxycarbonyl, amino, C1-C6-alkylamino, di(C1-C6-alkyl)amino, C1-C6-alkoxy, C1-C6-thioalkyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl;
X is halogen;
Y is hydrogen or halogen;
or the enantiomers or salts or N-oxides thereof, and
2) one or more compounds II selected from group A consisting of:
A1:
acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, flupyrazofos, isoxathion, malathion, methamidophos, methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, or trichlorfon;
A2:
alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, or triazamate;
A3:
allethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, or transfluthrin;
A4:
a) benzoylureas, bistrifluron, chlorfluazuron, cyromazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, or clofentezine;
b) halofenozide, methoxyfenozide, tebufenozide, or azadirachtin;
c) pyriproxyfen, methoprene, or fenoxycarb;
or d) spirodiclofen, spiromesifen, or spirotetramat, having the formula Γ1,
A5:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, or thiacloprid;
A6:
acetoprole, endosulfan, ethiprole, fipronil, pyrafluprole, pyriprole, or the phenylpyrazole compound of formula Γ2
A7:
abamectin, emamectin, milbemectin, lepimectin, or spinosad;
A8:
fenazaquin, pyridaben, tebufenpyrad, or tolfenpyrad;
A9:
acequinocyl, fluacypyrim, or hydramethylnon;
A10:
chlorfenapyr;
A11:
cyhexatin, diafenthiuron, fenbutatin oxide, or propargite;
A12:
piperonyl butoxide;
A13:
indoxacarb, or metaflumizone;
and
A14:
amidoflumet, benclothiaz, bifenazate, cartap, cyflumetofen, flonicamid, flufenerim, pyridalyl, pymetrozine, sulfur, thiocyclam or the aminoisothiazole compounds of formula Γ3,
wherein Ri is —CH2OCH2CH3 or H and Rii is CF2CF2CF3 or CH2CH(CH3)3,
wherein said compound of formula I and said one or more compounds II are present in synergistically effective amounts;
wherein said insects, arachnids or nematodes are controlled.

43 more elements

A method for protection of seed comprising,

contacting said seeds with a pesticidally effective amount of a mixture comprising, 1) a compound of the formula I
wherein,
B1 is halogen, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-haloalkoxy;
B2 is halogen, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-haloalkoxy-C1-C4-haloalkoxy, C1-C4-alkenyloxy, C1-C4-alkynyloxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkyl-S(═O)x—O— or C1-C4-haloalkyl S(O)x—O—, wherein x is 1 or 2 and the C1-C4-alkoxy radical may be substituted with 1-6 groups selected from halogen, cyano, C1-C4-alkoxy, C1-C4-alkoxycarbonyl;
R is hydrogen, ethyl, n-propyl, butyl, pentyl, hexyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, wherein these groups are unsubstituted or substituted with from 1 to 3 groups selected from halogen, cyano, nitro, C1-C6-alkyloxycarbonyl, amino, C1-C6-alkylamino, di(C1-C6-alkyl)amino, C1-C6-alkoxy, C1-C6-thioalkyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl;
X is halogen;
Y is hydrogen or halogen;
or the enantiomers or salts or N-oxides thereof, and
2) one or more compounds II selected from group A consisting of:
A1:
acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, flupyrazofos, isoxathion, malathion, methamidophos, methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, or trichlorfon;
A2:
alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, or triazamate;
A3:
allethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, or transfluthrin;
A4:
a) benzoylureas, bistrifluron, chlorfluazuron, cyromazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, or clofentezine;
b) halofenozide, methoxyfenozide, tebufenozide, or azadirachtin;
c) pyriproxyfen, methoprene, or fenoxycarb;
or d) spirodiclofen, spiromesifen, or spirotetramat, having the formula Γ1,
A5:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, or thiacloprid;
A6:
acetoprole, endosulfan, ethiprole, fipronil, pyrafluprole, pyriprole, or the phenylpyrazole compound of formula Γ2
A7:
abamectin, emamectin, milbemectin, lepimectin, or spinosad;
A8:
fenazaquin, pyridaben, tebufenpyrad, or tolfenpyrad;
A9:
acequinocyl, fluacypyrim, or hydramethylnon;
A10:
chlorfenapyr;
A11:
cyhexatin, diafenthiuron, fenbutatin oxide, or propargite;
A12:
piperonyl butoxide;
A13:
indoxacarb, or metaflumizone;
and
A14:
amidoflumet, benclothiaz, bifenazate, cartap, cyflumetofen, flonicamid, flufenerim, pyridalyl, pymetrozine, sulfur, thiocyclam or the aminoisothiazole compounds of formula Γ3,
wherein Ri is —CH2OCH2CH3 or H and Rii is CF2CF2CF3 or CH2CH(CH3)3,
wherein said compound of formula I and said one or more compounds II are present in synergistically effective amounts;
wherein said seed is protected.

42 more elements

A seed, comprising a pesticidal mixture in an amount of from 0.1 g to 10 kg per 100 kg said seed, said mixture comprising,

1) a compound of the formula I
wherein,
B1 is halogen, C1-Ca-alkyl, C1-C4-haloalkyl, or C1-C4-haloalkoxy;
B2 is halogen, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-haloalkoxy-C1-C4-haloalkoxy, C1-C4-alkenyloxy, C1-C4-alkynyloxy, C1-C4-alkylthio, C1-C4haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkyl-S(═O)x—O— or C1-C4-haloalkyl S(O)x—O—, wherein x is 1 or 2 and the C1-C4-alkoxy radical may be substituted with 1-6 groups selected from halogen, cyano, C1-C4-alkoxy, C1-C4-alkoxycarbonyl;
R is hydrogen, ethyl, n-propyl, butyl, pentyl, hexyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, wherein these groups are unsubstituted or substituted with from 1 to 3 groups selected from halogen, cyano, nitro, C1-C6-alkyloxycarbonyl, amino, C1-C6-alkylamino, di(C1-C6-alkyl)amino, C1-C6-alkoxy, C1-C6-thioalkyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl;
X is halogen;
Y is hydrogen or halogen;
or the enantiomers or salts or N-oxides thereof, and
2) one or more compounds II selected from group A consisting of:
A1:
acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, flupyrazofos, isoxathion, malathion, methamidophos, methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, or trichlorfon;
A2:
alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, or triazamate;
A3:
allethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, or transfluthrin;
A4:
a) benzoylureas, bistrifluron, chlorfluazuron, cyromazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, or clofentezine;
b) halofenozide, methoxyfenozide, tebufenozide, or azadirachtin;
c) pyriproxyfen, methoprene, or fenoxycarb;
or d) spirodiclofen, spiromesifen, or spirotetramat, having the formula Γ1,
A5:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, or thiacloprid;
A6:
acetoprole, endosulfan, ethiprole, fipronil, pyrafluprole, pyriprole, or the phenylpyrazole compound of formula Γ2
A7:
abamectin, emamectin, milbemectin, lepimectin, or spinosad;
A8:
fenazaquin, pyridaben, tebufenpyrad, or tolfenpyrad;
A9:
acequinocyl, fluacypyrim, or hydramethylnon;
A10:
chlorfenapyr;
A11:
cyhexatin, diafenthiuron, fenbutatin oxide, or propargite;
A12:
piperonyl butoxide;
A13:
indoxacarb, or metaflumizone;
and
A14:
amidoflumet, benclothiaz, bifenazate, cartap, cyflumetofen, flonicamid, flufenerim, pyridalyl, pymetrozine, sulfur, thiocyclam or the aminoisothiazole compounds of formula Γ3,
wherein Ri is —CH2OCH2CH3 or H and Rii is CF2CF2CF3 or CH2CH(CH3)3,
wherein said compound of formula I and said one or more compounds II are present in synergistically effective amounts.

41 more elements

A method for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by parasites comprising,

administering or applying to said animal or fish a parasiticidally effective amount of a mixture comprising,
1) a compound of the formula I
wherein,
B1 is halogen, C1-C4-alkyl, C1-C4-haloalkyl, or C1-C4-haloalkoxy;
B2 is halogen, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-haloalkoxy-C1-C4-haloalkoxy, C1-C4-alkenyloxy, C1-C4-alkynyloxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkyl-S(═O)x—O— or C1-C4-haloalkyl S(O)x—O—, wherein x is 1 or 2 and the C1-C4-alkoxy radical may be substituted with 1-6 groups selected from halogen, cyano, C1-C4-alkoxy, C1-C4-alkoxycarbonyl;
R is hydrogen, ethyl, n-propyl, butyl, pentyl, hexyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, wherein these groups are unsubstituted or substituted with from 1 to 3 groups selected from halogen, cyano, nitro, C1-C6-alkyloxycarbonyl, amino, C1-C6-alkylamino, di(C1-C6-alkyl)amino, C1-C6-alkoxy, C1-C6-thioalkyl, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl;
X is halogen;
Y is hydrogen or halogen;
or the enantiomers or salts or N-oxides thereof, and
2) one or more compounds II selected from group A consisting of:
A1:
acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, flupyrazofos, isoxathion, malathion, methamidophos, methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, or trichlorfon;
A2:
alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, or triazamate;
A3:
allethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, or transfluthrin;
A4:
a) benzoylureas, bistrifluron, chlorfluazuron, cyromazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, or clofentezine;
b) halofenozide, methoxyfenozide, tebufenozide, or azadirachtin;
c) pyriproxyfen, methoprene, or fenoxycarb;
or d) spirodiclofen, spiromesifen, or spirotetramat, having the formula Γ1,
A5:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, or thiacloprid;
A6:
acetoprole, endosulfan, ethiprole, fipronil, pyrafluprole, pyriprole, or the phenylpyrazole compound of formula Γ2
A7:
abamectin, emamectin, milbemectin, lepimectin, or spinosad;
A8:
fenazaquin, pyridaben, tebufenpyrad, or tolfenpyrad;
A9:
acequinocyl, fluacypyrim, or hydramethylnon;
A10:
chlorfenapyr;
A11:
cyhexatin, diafenthiuron, fenbutatin oxide, or propargite;
A12:
piperonyl butoxide;
A13:
indoxacarb, or metaflumizone;
and
A14:
amidoflumet, benclothiaz, bifenazate, cartap, cyflumetofen, flonicamid, flufenerim, pyridalyl, pymetrozine, sulfur, thiocyclam or the aminoisothiazole compounds of formula Γ3,
wherein Ri is —CH2OCH2CH3 or H and Rii is CF2CF2CF3 or CH2CH(CH3)3,
wherein said compound of formula I and said one or more compounds II are present in synergistically effective amounts;
wherein said animal or fish is treated, controlled, prevented or protected against said infestation or infection.

43 more elements

Dependencies are inferred from the claim text.

Pesticidal Mixtures

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Pesticidal Mixtures

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Abstract

Claims22