Recycling of superalloys with the aid of an alkali metal salt bath
AssigneeH.C. Starck GmbH
InventorsArmin Olbrich, Juliane Meese-Marktscheffel, Matthias Jahn, Rüdiger Zertani, Viktor Stoller, Michael Erb, Karl-Heinz Heine, Uwe Kutzler
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Abstract
The invention relates to a process for recovering valuable metals from a superalloy which has the steps of digesting the superalloy in a salt melt. The salt melt contains 60-95% by weight of NaOH and 5-40% by weight of Na2SO4.
Claims22
1-21. (canceled)
A process for recovering valuable metals from a superalloy which comprises digesting the superalloy in a salt melt containing 60-95% by weight of NaOH and 5-40% by weight of Na2SO4.
A process for obtaining rhenium from a superalloy consisting of the following steps:
- a) digesting the superalloy in a salt melt consisting essentially of 60-95% by weight of NaOH and 5-40% by weight of Na2SO4,
- b) cooling of the melt to room temperature,
- c) commination of the melt digestion product,
- d) reacting of the comminuted melt digestion product in water at temperatures of less than 80° C. and production of an aqueous suspension containing
- a solution consisting of a mixture of sodium compounds from the group consisting of NaOH, Na2SO4, NaAl(OH)4 and/or Na2CO3 and alkali metallates of the elements of the 6th and/or 7th subgroup of the Periodic Table of the Elements;
- a solid metallic phase consisting of the group of metals Co, Ni, Fe, Mn and Cr;
- a solid phase consisting of hydroxides and/or hydrated oxides of the metals of the 3rd main group and of metals of the 4th and/or 5th subgroup of the Periodic Table of the Elements,
- e) removing of the aqueous fraction by filtration, and
- f) removing of the rhenium from the aqueous fraction.
Dependencies are inferred from the claim text.