Mesoporous Metal-Organic Framework
AssigneeBASF SE
InventorsMarkus Schubert, Ulrich Muller, Hendrick Mattenheimer, Markus Tonigold
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AssigneeBASF SE
InventorsMarkus Schubert, Ulrich Muller, Hendrick Mattenheimer, Markus Tonigold
Estimating the term…
The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.
A porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, wherein the at least one metal ion is AlIII and the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof, characterized in that the metal-organic framework in powder has a specific surface area determined by the Langmuir method of at least 800 m2/g.
(canceled)
The method according to claim 14 for the storage of hydrogen.
The method according to claim 14 for diffusion-limited reaction with large-volume reactants.
Dependencies are inferred from the claim text.