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US 12,770,888 B2Granted
Catalyst for fuel cell and method for preparing the same
AssigneesHyundai Motor Company, Kia Corporation
InventorsJee Youn Hwang, Eunjik Lee, Dahee Kwak, Ji-Hoon Jang, Songi Oh
Life of this patent
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Abstract
A catalyst for a fuel cell includes: a crystalline carbon support having a specific surface area of about 200 m2/g to about 500 m2/g; and intermetallic active particles of a transition metal and a noble metal, wherein the intermetallic active particles are supported on the crystalline carbon support and have a particle diameter of greater than or equal to about 3 nm.
Claims8
A method of preparing a catalyst for a fuel cell, the method comprising:
- irradiating ultrasonic waves to a precursor mixed solution including a noble metal precursor, a transition metal precursor, and a crystalline carbon support having a specific surface area of about 200 m2/g to about 500 m2/g, and forming core-shell particles including a transition metal oxide coating layer;
- annealing the core-shell particles and forming intermetallic particles including a transition metal oxide coating layer;
- and
- removing the transition metal oxide coating layer from the intermetallic particles, and
- wherein the catalyst comprises the crystalline carbon support, and intermetallic active particles of a transition metal and a noble metal,
- wherein the intermetallic active particles are supported on the crystalline carbon support and have a particle diameter of greater than or equal to about 3 nm, and
- wherein the catalyst comprises more than about 0% and about 40% or less by number of the intermetallic active particles embedded in pores of the carbon support, and more than about 60% and about 100% or less by number of the intermetallic active particles present in a surface of the carbon support with respect to a total number of the intermetallic active particles,
- wherein the intermetallic active particles comprise an intermetallic core of the transition metal and the noble metal, and a noble metal skin layer surrounding the intermetallic core,
- wherein the noble metal comprises platinum (Pt) and the transition metal comprises iron (Fe),
- wherein the crystalline carbon support has a carbon shell thickness of about 3 nm to about 6 nm;
- and
- wherein the core-shell particles comprise a transition metal core, a noble metal shell surrounding the transition metal core, and a transition metal oxide coating layer surrounding the noble metal shell.
9 more elements
Dependencies are inferred from the claim text.