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US 12,753,119 B2Granted
Uncharged clay blocking agent
AssigneeBASF SE
InventorsManfred Bichler, Alexander Schoebel, Alexander Ganss
Life of this patent
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Abstract
The present invention relates to a construction material composition comprising at least one non-ionic copolymer and the use of said construction material composition. Further, the present invention relates to a non-ionic copolymer and the use thereof for modifying robustness against clay deviations.
Claims9
A construction material composition comprising
- A) at least one non-ionic copolymer, wherein the copolymer is uncharged at a pH range of 5 to 9, comprising residues based on the following monomer components:
- i) monomer Component A, comprising an ethylenically unsaturated monomer comprising at least one alkyl amide moiety or at least one nitrogen-containing heterocyclic moiety, and
- ii) monomer Component B, comprising an ethylenically unsaturated monomer comprising at least one polyether moiety, wherein the at least one polyether moiety in monomer Component B comprises the structural unit (a)
- *—U—(C(O))k—X-(AlkO)n—W (a)
- wherein
- * denotes the binding site to the polymer,
- U is a chemical bond or a C1-C8-alkylene,
- X is O, N, or NR1,
- k is 0 or 1,
- n is an integer having a mean value of between 24 to 300, based on the whole non-ionic copolymer,
- Alk is C2-C4-alkylene, wherein Alk may be same or different within the group of (AlkO)n,
- W is H, C1-C6-alkyl, aryl, or Y—F,
- Y is a linear or branched C2-C8-alkylene, which may further be substituted with a phenyl,
- F is a 5 to 10-membered nitrogen heterocycle, which is attached via a nitrogen to Y, wherein besides the nitrogen atom and carbon atoms 1, 2, or 3 additional heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur may be present as ring members and wherein the nitrogen ring members may be bond to a moiety R2, and wherein 1 or 2 carbon ring members may be present as carbonyl,
- R1 is H, C1-C4-alkyl, or benzyl, and
- R2 is H, C1-C4-alkyl, or benzyl;
- and
- B) at least one inorganic binder based on calcium sulfate.
15 more elements
A construction material composition comprising
- A) at least one non-ionic copolymer, wherein the copolymer is uncharged at a pH range of 5 to 9, comprising residues based on the following monomer components:
- i) monomer Component A, comprising an ethylenically unsaturated monomer comprising at least one alkyl amide moiety or at least one nitrogen-containing heterocyclic moiety, and
- ii) monomer Component B, comprising an ethylenically unsaturated monomer comprising at least one polyether moiety, wherein the at least one polyether moiety in monomer Component B comprises the structural unit (a)
- *—U—(C(O))k—X-(AlkO)n—W (a)
- wherein
- * denotes the binding site to the polymer,
- U is a chemical bond or a C2-C8-alkylene,
- X is O, N, or NR1,
- k is 0 or 1,
- n is an integer having a mean value of between 24 to 300, based on the whole non-ionic copolymer,
- Alk is C2-C4-alkylene, wherein Alk may be same or different within the group of (AlkO)n,
- W is H, C1-C6-alkyl, aryl, or Y—F,
- Y is a linear or branched C2-C8-alkylene, which may further be substituted with a phenyl,
- F is a 5 to 10-membered nitrogen heterocycle, which is attached via a nitrogen to Y, wherein besides the nitrogen atom and carbon atoms 1, 2, or 3 additional heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur may be present as ring members and wherein the nitrogen ring members may be bond to a moiety R2, and wherein 1 or 2 carbon ring members may be present as carbonyl,
- R1 is H, C1-C4-alkyl, or benzyl, and
- R2 is H, C1-C4-alkyl, or benzyl,
- with the proviso that k is 0 if U is a chemical bond;
- and
- B) at least one inorganic binder selected from a hydraulic binder or a latent hydraulic binder.
16 more elements
A method comprising providing a non-ionic copolymer, wherein the copolymer is uncharged at a pH range of 5 to 9,
- comprising residues based on the following monomer components:
- i) monomer Component A, comprising an ethylenically unsaturated monomer comprising at least one alkyl amide moiety or at least one nitrogen-containing heterocyclic moiety;
- ii) monomer Component B, comprising an ethylenically unsaturated monomer comprising at least one polyether moiety comprising the structural unit (a)
- *—U—(C(O))k-X-(AlkO)n-W (a)
- wherein
- * denotes the binding site to the polymer,
- U is a chemical bond or a C1-C8-alkylene,
- X is O, N, or NR1,
- k is o or 1,
- n is an integer having a mean value of between 3 to 300, based on the whole non-ionic copolymer,
- Alk is C2-C4-alkylene, wherein Alk may be same or different within the group of (AlkO) n,
- W is H, C1-C6-alkyl, aryl, or Y—F,
- Y is a linear or branched C2-C8-alkylene, which may further be substituted with a phenyl,
- F is a 5 to 10-membered nitrogen heterocycle, which is attached via a nitrogen to Y, wherein besides the nitrogen atom and carbon atoms 1, 2, or 3 additional heteroatoms selected from the group consisting of oxygen, nitrogen, and sulfur may be present as ring members and wherein the nitrogen ring members may be bond to a moiety R2, and wherein 1 or 2 carbon ring members may be present as carbonyl,
- R1 is H, C1-C4-alkyl, or benzyl, and
- R2 is H, C1-C4-alkyl, or benzyl;
- and
- at least one inorganic binder selected from a hydraulic binder or a latent hydraulic binder or at least one inorganic binder based on calcium sulfate, and
- iii) optionally monomer Component C, having the formula (1) wherein
- RA is H, OH, (C1-C3-alkylene)-OH, or C1-C3-alky;
- RB is H, OH, (C1-C3-alkylene)-OH, or C1-C3-alky;
- RC is H, OH, (C1-C3-alkylene)-OH, or C1-C3-alky;
- and
- n is an integer from o to 10,
- preparing a construction material composition,
- and modifying robustness against clay deviations, without retarding the set time of the construction material composition.
23 more elements
Dependencies are inferred from the claim text.