A particulate composition for additive manufacturing comprising or consisting of, a polyhydroxyalkanoate (PHA) powder, wherein the PHA powder comprises or consists of poly-3-hydroxybutyrate (P3HB), poly-4-hydroxybutyrate (P4HB), polyhydroxyvalerate (PHV), polyhydroxyhexanoate (PHH), or copolymers thereof, and wherein the PHA powder possesses
- a. a free bulk density, as determined by ASTM D1895-96, of greater than 0.30 g/mL, and
- b. a sinterability region of greater than 15 degrees Celsius, wherein the sinterability region is determined by a value of Ti,m minus Tf,c per ISO 11357-1 (2009).