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US 12,644,065 B2Granted
Biofuel derived from glycerol esters and method for obtaining same
OwnerRodolfo Wattson Gomezinventor
Life of this patent
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Abstract
The present invention relates to a combustion additive comprising iron oxide nanoparticles; a fuel based on natural plant and animal fats and oils; and a method for producing the same. The production method allows up to 100% of the raw material, both virgin and waste fats and oils, to be used. The combustion additive and the fuel are useful in the combustion process; for example, in diesel-type alternative combustion engines.
Claims17
Method for preparing an iron nanoparticle combustion additive and a fuel from fats, oils or a mixture of both, comprising the steps of:
- a. purifying crude fats and/or oils to remove rubber, phospholipids, lipids, and particles;
- b. reacting with free fatty acids or activated fatty acids, in excess, by interesterification, transesterification or acidolysis, in the presence of a suitable catalyst, of the fats and/or oils purified from the previous stage to obtain triacylglycerol with suitable viscosity, free fatty acids of different chain sizes, acylglycerols and others;
- c. fractioning the mixture obtained from stage b to obtain a rich in free or activated medium or long chain fatty acids fraction, from 6 to 20 carbon atoms, a rich in free or activated short chain fatty acids fraction (2 to 6 carbon atoms), and a rich in triacylglycerols and acylglycerols fraction;
- d. reacting the rich in medium or long chain fatty acids fraction, in an oxygen-free alkaline environment, with iron salts in the presence of an oxidizing agent;
- e. filtering or settling the precipitate obtained from stage d, to obtain a partially moist solid;
- f. drying the partially moist solid obtained from step e, to obtain an agglomerated powder of iron hydroxides;
- g. calcining the agglomerated powder of iron hydroxides obtained from step £ to obtain an iron nanoparticles additive;
- h. emulsifying the rich in triacylglycerols and acylglycerols fraction with hydrogen peroxide or the iron nanoparticles additive obtained from step g. or a mixture of both, in the presence of a surfactant, to obtain a fuel.
5 more elements
Dependencies are inferred from the claim text.