Polyester resin composition, aqueous dispersion, coating composition, and coating film
AssigneeTOYOBO MC Corporation
InventorsHiroyuki Mieda, Katsuya Shimeno, Tadahiko Mikami
Life of this patent
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Abstract
It is provided that a polyester resin and a polyester resin composition that allow reduction of harmful outgas and can form a coating film having excellent characteristics such as curability, retort resistance, and processability. A polyester resin composition comprising polyester resin (A), wherein the polyester resin composition satisfies the following requirements (i) to (iii), (i) the polyester resin (A) has an acid value of 100 eq/ton or more, (ii) the polyester resin composition substantially contains no curing agent, and (iii) a content of tetrahydrofuran-insoluble matter is 10 mass % or more when the polyester resin composition has been heated at 240° C. for one hour.
Claims17
A polyester resin composition comprising a polyester resin (A) and one or more kinds of catalysts (B), wherein the polyester resin composition satisfies the following requirements (i) to (iv),
- (i) the polyester resin (A) has an acid value of 100 eq/ton or more,
- (ii) in terms of solid content, a content of a curing agent is smaller than 1 part by mass with respect to 100 parts by mass of the polyester resin (A),
- (iii) a content of tetrahydrofuran-insoluble matter obtained by the following equation when the polyester resin composition has been heated at 240° C. for one hour is 10 mass % or more:
- Content of tetrahydrofuran-insoluble matter (mass %)=[{(Y)−mass of copper foil}/{(X)−mass of copper foil}]×100,
- wherein the polyester resin composition is applied onto a copper foil such that the thickness is 10 μm after being dried, heat is applied at 240° C. for one hour, and a sample having a longitudinal direction of 10 cm and a transverse direction of 2.5 cm is obtained, and a mass of the sample before immersion in tetrahydrofuran is defined as (X), and a mass of the sample which has been immersed in 60 ml of tetrahydrofuran at 25° C. for one hour, and thereafter dried at 100° C. for 10 minutes, is defined as (Y) after immersion in tetrahydrofuran, and
- (iv) a content of the one or more kinds of catalysts (B) is 0.01 to 0.5 parts by mass with respect to 100 parts by mass of the polyester resin (A).
Dependencies are inferred from the claim text.