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US 12,590,249 B2Granted
Etchant composition
AssigneeSamsung Electronics Co., Ltd.
InventorsJung-ah Kim, Young-chan Kim, Hyo-san Lee, Hoon Han, Jin-uk Lee, Jung-hun Lim, Ik-hee Kim
Life of this patent
Estimating the term…
Abstract
An etchant composition and a method of fabricating a semiconductor device, the composition including an inorganic acid; about 0.01 parts by weight to about 0.5 parts by weight of colloidal silica; about 0.01 parts by weight to about 30 parts by weight of an ammonium-based additive; and about 20 parts by weight to about 50 parts by weight of a solvent, all parts by weight being based on 100 parts by weight of the inorganic acid.
Claims16
An etchant composition, comprising:
- an inorganic acid;
- about 0.01 parts by weight to about 0.5 parts by weight of colloidal silica;
- about 0.01 parts by weight to about 30 parts by weight of an ammonium additive;
- and
- about 20 parts by weight to about 50 parts by weight of a solvent,
- all parts by weight being based on 100 parts by weight of the inorganic acid,
- wherein the colloidal silica has a structure represented by Chemical Formula 1, the structure being formed under acidic conditions at a pH of 1 or less and a temperature of 200° C. or higher:
- wherein, in Chemical Formula 1,
- m is an integer of 2 to 8, and
- R1, R2, R3, R4, R5, R6, R7, and R8 are each independently a hydrogen atom, a hydroxyl group, or a group represented by Chemical Formula 2, at least one of R1, R2, R3, R4, R5, R6, R7, and R8 being a hydroxyl group or a group represented by Chemical Formula 2,
- wherein, in Chemical Formula 2,
- n is an integer of 0 to 5, and
- R9 and R10 are each independently a hydrogen atom, a hydroxyl group, a C1 to C20 alkyl group, a C2 to C20 alkenyl group, a C2 to C20 alkynyl group, a C1 to C20 hydroxyalkyl group, a C1 to C20 aminoalkyl group, a C1 to C20 alkoxy group, a C1 to C20 aminoalkoxy group, a nitrile group, or a carboxyl group, and
- wherein the etchant composition has a pH of 1 or less and a temperature of 200° C. or higher.
11 more elements
An etchant composition, comprising:
- an inorganic acid;
- about 0.01 parts by weight to about 0.5 parts by weight of colloidal silica;
- about 0.1 parts by weight to about 20 parts by weight of an ammonium additive;
- and
- about 20 parts by weight to about 50 parts by weight of a solvent,
- all parts by weight being based on 100 parts by weight of the inorganic acid,
- wherein the colloidal silica has a structure represented by Chemical Formula 1, the structure being formed under acidic conditions at a pH of 1 or less and a temperature of 200° C. or higher:
- wherein, in Chemical Formula 1,
- m is an integer of 2 to 8, and
- R1, R2, R3, R4, R5, R6, R7, and R8 are each independently a hydrogen atom, a hydroxyl group, or a group represented by Chemical Formula 2, at least one of R1, R2, R3, R4, R5, R6, R7, and R8 being a hydroxyl group or a group represented by Chemical Formula 2,
- wherein, in Chemical Formula 2,
- n is an integer of 0 to 5, and
- R9 and R10 are each independently a hydrogen atom, a hydroxyl group, a C1 to C20 alkyl group, a C2 to C20 alkenyl group, a C2 to C20 alkynyl group, a C1 to C20 hydroxyalkyl group, a C1 to C20 aminoalkyl group, a C1 to C20 alkoxy group, a C1 to C20 aminoalkoxy group, a nitrile group, or a carboxyl group, and
- wherein the etchant composition further comprises about 0.01% by weight (wt %) to about 1 wt % of a fluorine compound, and
- wherein the etchant composition has a pH of 1 or less and a temperature of 200° C. or higher.
12 more elements
Dependencies are inferred from the claim text.