Antifouling coating composition and antifouling coating film
AssigneeNippon Paint Marine Coatings Co., Ltd.
InventorsTomoya Mori, Yasuhisa Nagase, Mamoru Shimada
Life of this patent
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Abstract
Provided is an antifouling coating composition comprising a silicon atom-containing resin. The silicon atom-containing resin includes a constituent unit (A) derived from a monomer (a) having at least one kind of silicon atom-containing group selected from the group consisting of a group represented by a formula (I), a group represented by a formula (II), a group represented by a formula (III), and a group represented by a formula (IV); and a constituent unit (B) derived from a monomer (b) which is a polyfunctional (meth)acrylic acid ester having two or more (meth)acryloyl groups.
Claims16
An antifouling coating composition comprising a silicon atom-containing resin,
- wherein
- the silicon atom-containing resin includes:
- a constituent unit (A) derived from a monomer (a) having at least one kind of silicon atom-containing group selected from the group consisting of a group represented by a formula (I) below, a group represented by a formula (II) below, a group represented by a formula (III) below, and a group represented by a formula (IV) below;
- and
- a constituent unit (B) derived from a monomer (b) which is a polyfunctional (meth)acrylic acid ester having two or more (meth)acryloyloxy groups:
- [Chemical formula 1]
- in the formula (I), a and b each independently represent an integer of 2 to 5, m represents an integer of 0 to 50, and n represents an integer of 3 to 270;
- and R1 to R5 each independently represent an alkyl group, an alkoxy group, a phenyl group, a substituted phenyl group, a phenoxy group, or a substituted phenoxy group;
- [Chemical formula 2]
- in the formula (II), c and d each independently represent an integer of 2 to 5, and p represents an integer of 0 to 50;
- R6, R7 and R8 each independently represent an alkyl group, Ra, or Rb;
- Ra is
- [Chemical formula 3]
- in the formula, x represents an integer of 0 to 200, and R23 to R27 are the same or different and each represent an alkyl group;
- and
- Rb is
- [Chemical formula 4]
- in the formula, y represents an integer of 1 to 200, and R28 and R29 are the same or different and each represent an alkyl group;
- [Chemical formula 5]
- in the formula (III), e, f, g, and h each independently represent an integer of 2 to 5, q and s each independently represent an integer of 0 to 50, and r represents an integer of 3 to 270;
- and R9 to R12 each independently represent an alkyl group, an alkoxy group, a phenyl group, a substituted phenyl group, a phenoxy group, or a substituted phenoxy group;
- [Chemical formula 6]
- in the formula (IV), i, j, k, and l each independently represent an integer of 2 to 5, t and u each independently represent an integer of 0 to 50, and v and w each independently represent an integer of 0 to 70;
- and R13 to R22 are the same or different and each represent an alkyl group, and
- wherein a content of the constituent unit (B) is less than or equal to 30 mass % in all constituent units contained in the silicon atom-containing resin, and the monomer (b) is a compound (b-1) represented by a formula (b-1) below
- in the formula (b-1), RA each independently represents a hydrogen atom or a methyl group, RB represents a divalent hydrocarbon group that may have a substituent, and at least one-CH2-of the hydrocarbon group may be replaced by—O—or —C (═0)—1.
Dependencies are inferred from the claim text.